HESI A2
HESI A2 Chemistry
1. What is the energy required to remove the outermost electron from an atom called?
- A. covalent bonding
- B. electronegativity
- C. atomic radius
- D. ionization energy
Correct answer: D
Rationale: Ionization energy is the energy needed to remove the outermost electron from an atom, resulting in the formation of a positively charged ion. The higher the ionization energy, the more difficult it is to extract an electron. Electronegativity, however, measures an atom's ability to attract shared electrons in a chemical bond. Atomic radius refers to the distance from the nucleus to the outermost electron. Covalent bonding involves sharing electron pairs between atoms to create a stable bond. Therefore, the correct answer is ionization energy as it specifically relates to the energy needed to remove an electron from an atom.
2. Which compound has a nonpolar bond in which the electrons are shared equally?
- A. Hâ‚‚O
- B. NH₃
- C. Clâ‚‚
- D. CHâ‚„
Correct answer: D
Rationale: The compound CH₄, methane, has a nonpolar bond where carbon and hydrogen share electrons equally. This occurs because carbon and hydrogen have similar electronegativities, meaning they have equal abilities to attract shared electrons. Consequently, a nonpolar covalent bond is formed due to the balanced sharing of electrons between these atoms. Choices A, B, and C do not have nonpolar bonds with electrons shared equally. In H₂O (water), there are polar covalent bonds due to the difference in electronegativity between hydrogen and oxygen. In NH₃ (ammonia), the nitrogen-hydrogen bonds are polar because of the electronegativity difference. In Cl₂ (chlorine gas), the Cl-Cl bond is nonpolar, but the question specifies a compound, not an element, and chlorine does not share its electrons equally with another element in a compound.
3. What are the products of combustion of a hydrocarbon in excess oxygen?
- A. Carbon dioxide and water
- B. Naphthalene
- C. Chlorine and bromine
- D. Carbonium ions
Correct answer: A
Rationale: The correct answer is A: Carbon dioxide and water. During the combustion of a hydrocarbon in excess oxygen, the hydrocarbon reacts to produce carbon dioxide and water vapor as the final products. This reaction is known as complete combustion, where the hydrocarbon combines with oxygen to form carbon dioxide and water. Choices B, C, and D are incorrect because naphthalene is a specific hydrocarbon compound, chlorine and bromine are not typically formed during the combustion of hydrocarbons in excess oxygen, and carbonium ions are not the products of this reaction.
4. What is the chemical symbol for sodium?
- A. N
- B. Na
- C. Cl
- D. H
Correct answer: B
Rationale: The correct chemical symbol for sodium is 'Na.' In the periodic table, sodium is represented by the symbol 'Na,' derived from its Latin name 'natrium.' The symbol 'N' represents nitrogen, not sodium. 'Cl' is the symbol for chlorine, and 'H' is the symbol for hydrogen. Therefore, 'Na' is the correct chemical symbol for sodium.
5. Here are the solubilities of four substances at 0°C, in grams of solute per 100 mL of water. If the temperature increases to 20°C, what would you expect to happen to the solubility figures?
- A. Citric acid and potassium phosphate will decrease; nitrogen and oxygen will increase.
- B. Citric acid and potassium phosphate will increase; nitrogen and oxygen will decrease.
- C. All four figures will increase.
- D. All four figures will decrease.
Correct answer: C
Rationale: Solubility generally tends to increase with temperature for most solid solutes in liquid solvents due to higher kinetic energy leading to better solute-solvent interactions. As the temperature increases from 0°C to 20°C, all four solubility figures are expected to increase. Choice A is incorrect because solubility tends to increase with temperature. Choice B is incorrect as well for the same reason. Choice D is incorrect because the solubility of solid solutes typically increases with temperature.
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