HESI A2
HESI A2 Chemistry
1. What is the energy required to remove the outermost electron from an atom called?
- A. covalent bonding
- B. electronegativity
- C. atomic radius
- D. ionization energy
Correct answer: D
Rationale: Ionization energy is the energy needed to remove the outermost electron from an atom, resulting in the formation of a positively charged ion. The higher the ionization energy, the more difficult it is to extract an electron. Electronegativity, however, measures an atom's ability to attract shared electrons in a chemical bond. Atomic radius refers to the distance from the nucleus to the outermost electron. Covalent bonding involves sharing electron pairs between atoms to create a stable bond. Therefore, the correct answer is ionization energy as it specifically relates to the energy needed to remove an electron from an atom.
2. What is the name of the bond formed when two atoms share electrons?
- A. Covalent bond
- B. Ionic bond
- C. Metallic bond
- D. Hydrogen bond
Correct answer: A
Rationale: A covalent bond is formed when two atoms share electrons, creating a stable electron configuration. This sharing allows both atoms to achieve a full outer shell of electrons, leading to a stable molecule. In contrast, an ionic bond involves the transfer of electrons from one atom to another, resulting in the formation of ions with opposite charges. Metallic bonds are formed between metal atoms and involve a 'sea of electrons' that are delocalized and free to move. Hydrogen bonds are a type of intermolecular force, not a true chemical bond, and occur between a hydrogen atom and a highly electronegative atom like oxygen or nitrogen.
3. Which compound has a nonpolar bond in which the electrons are shared equally?
- A. H₂O
- B. NH₃
- C. Cl₂
- D. CH₄
Correct answer: D
Rationale: The compound CH₄, methane, has a nonpolar bond where carbon and hydrogen share electrons equally. This occurs because carbon and hydrogen have similar electronegativities, meaning they have equal abilities to attract shared electrons. Consequently, a nonpolar covalent bond is formed due to the balanced sharing of electrons between these atoms. Choices A, B, and C do not have nonpolar bonds with electrons shared equally. In H₂O (water), there are polar covalent bonds due to the difference in electronegativity between hydrogen and oxygen. In NH₃ (ammonia), the nitrogen-hydrogen bonds are polar because of the electronegativity difference. In Cl₂ (chlorine gas), the Cl-Cl bond is nonpolar, but the question specifies a compound, not an element, and chlorine does not share its electrons equally with another element in a compound.
4. Which element has an atomic mass greater than that of sodium?
- A. Boron
- B. Oxygen
- C. Fluorine
- D. Silicon
Correct answer: D
Rationale: Silicon has an atomic mass greater than that of sodium. The atomic mass of silicon is approximately 28.0855 u, whereas the atomic mass of sodium is approximately 22.9898 u. Therefore, silicon has a greater atomic mass compared to sodium. Boron, Oxygen, and Fluorine have atomic masses lower than sodium, making them incorrect choices in this context.
5. Which element is considered a noble gas?
- A. Oxygen
- B. Neon
- C. Hydrogen
- D. Argon
Correct answer: B
Rationale: The correct answer is 'Neon.' Noble gases are a group of elements with very low reactivity. Neon is one of these elements, known for its stable and unreactive nature. Oxygen, hydrogen, and argon do not belong to the noble gas group. Oxygen is a reactive non-metal, hydrogen is a non-metal and the first element in the periodic table, and argon is a noble gas like neon but not the correct answer in this case.
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