HESI A2
HESI A2 Chemistry Questions
1. What is the name of the group of elements that contains chlorine, fluorine, and iodine?
- A. Alkali metals
- B. Halogens
- C. Transition metals
- D. Noble gases
Correct answer: B
Rationale: The correct answer is 'Halogens.' Halogens are a group of elements that include chlorine, fluorine, and iodine. These elements are part of Group 17 in the periodic table. They share similar properties such as high reactivity and the ability to readily form compounds. Choice A, 'Alkali metals,' is incorrect as alkali metals are found in Group 1 of the periodic table, which includes elements like lithium and sodium. Choice C, 'Transition metals,' is incorrect as transition metals are located in the middle section of the periodic table, not in Group 17. Choice D, 'Noble gases,' is incorrect as noble gases are in Group 18 and include elements like helium and neon, which are chemically inert.
2. How can water be boiled at room temperature?
- A. By lowering the pressure
- B. By increasing the pressure
- C. By decreasing the volume
- D. By raising the boiling point
Correct answer: A
Rationale: The boiling point of water is directly affected by pressure. By lowering the pressure, water can boil at a lower temperature, even at room temperature. This occurs because at lower pressures, the molecules of water have less resistance to escaping into the vapor phase, thus enabling boiling to occur at lower temperatures. Choices B, C, and D are incorrect because increasing the pressure, decreasing the volume, or raising the boiling point would actually require higher temperatures to boil water rather than achieving boiling at room temperature.
3. Which of the following elements does not exist as a diatomic molecule?
- A. boron
- B. fluorine
- C. oxygen
- D. nitrogen
Correct answer: A
Rationale: The correct answer is 'boron.' Diatomic molecules consist of two atoms of the same element bonded together. Boron is an exception and does not exist naturally as a diatomic molecule. On the other hand, fluorine, oxygen, and nitrogen commonly exist as diatomic molecules in their natural states. Fluorine, for example, exists as F2, oxygen exists as O2, and nitrogen exists as N2.
4. Which compound has a nonpolar bond in which the electrons are shared equally?
- A. H₂O
- B. NH₃
- C. Cl₂
- D. CH₄
Correct answer: D
Rationale: The compound CH₄, methane, has a nonpolar bond where carbon and hydrogen share electrons equally. This occurs because carbon and hydrogen have similar electronegativities, meaning they have equal abilities to attract shared electrons. Consequently, a nonpolar covalent bond is formed due to the balanced sharing of electrons between these atoms. Choices A, B, and C do not have nonpolar bonds with electrons shared equally. In H₂O (water), there are polar covalent bonds due to the difference in electronegativity between hydrogen and oxygen. In NH₃ (ammonia), the nitrogen-hydrogen bonds are polar because of the electronegativity difference. In Cl₂ (chlorine gas), the Cl-Cl bond is nonpolar, but the question specifies a compound, not an element, and chlorine does not share its electrons equally with another element in a compound.
5. What are the two types of chemical bonding?
- A. Covalent & hydrogen
- B. Ionic & covalent
- C. Ionic & hydrogen
- D. Covalent & metallic
Correct answer: B
Rationale: The correct answer is B: Ionic & covalent. Ionic bonding involves the transfer of electrons between atoms, resulting in the formation of positive and negative ions attracted to each other. Covalent bonding involves the sharing of electrons between atoms to achieve a stable electron configuration. Choice A is incorrect as hydrogen bonding is a type of intermolecular force, not a primary type of chemical bonding. Choice C is incorrect as hydrogen bonding is not a primary type of chemical bonding. Choice D is incorrect as metallic bonding involves the sharing of electrons in a 'sea of electrons' within a metal lattice, not covalent bonding.
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