HESI A2
HESI A2 Chemistry Practice Questions
1. How many moles of potassium bromide are in 25 mL of a 4 M KBr solution?
- A. 0.035 mol
- B. 0.1 mol
- C. 0.18 mol
- D. 1.6 mol
Correct answer: B
Rationale: To find the moles of potassium bromide in 25 mL of a 4 M KBr solution, we first need to convert the volume from milliliters to liters. 25 mL is equal to 0.025 L. Then, we use the formula moles = molarity x volume in liters. Substituting the values, moles = 4 M x 0.025 L = 0.1 mol. Therefore, there are 0.1 moles of KBr in 25 mL of a 4 M solution. Choice A, 0.035 mol, is incorrect as it does not properly calculate the moles. Choice C, 0.18 mol, and choice D, 1.6 mol, are also incorrect as they are not the result of the correct calculation based on the given molarity and volume.
2. Which of the following best describes an endothermic reaction?
- A. A reaction that absorbs heat
- B. A reaction that releases heat
- C. A reaction that does not involve heat
- D. A reaction that remains at a constant temperature
Correct answer: A
Rationale: An endothermic reaction is a process that absorbs heat from its surroundings. When a reaction absorbs heat, it leads to a decrease in the temperature of the surroundings, making choice A the correct description. In an endothermic reaction, energy is taken in from the surroundings, resulting in a decrease in temperature around the reaction site. Choice B is incorrect because a reaction that releases heat is known as an exothermic reaction. Choice C is incorrect as all reactions involve heat to some extent. Choice D is incorrect as an endothermic reaction does not remain at a constant temperature but rather absorbs heat, leading to a temperature decrease in the surroundings.
3. What is a balanced equation?
- A. A description where reactants and products are not equal
- B. An equation where the number of each type of atom is the same on both sides
- C. A chemical formula showing only reactants
- D. An equation without coefficients
Correct answer: B
Rationale: A balanced equation is one where the number of each type of atom is the same on both sides, fulfilling the law of conservation of mass. This principle ensures that the total number of atoms of each element is equal in both reactants and products, signifying that no atoms are created or destroyed, but rather rearranged. Choice A is incorrect because a balanced equation has equal numbers of atoms in the reactants and products. Choice C is incorrect as a balanced equation includes both reactants and products. Choice D is incorrect because coefficients are essential in balancing equations by adjusting the number of atoms present.
4. On the periodic table, where are atoms with the largest atomic radius located?
- A. At the top of their group
- B. In the middle of their group
- C. At the bottom of their group
- D. Along the right-hand side
Correct answer: C
Rationale: Atoms with the largest atomic radius are located at the bottom of their group on the periodic table. This is because atomic radius increases down a group due to the addition of more energy levels or shells of electrons. As you move down a group, the outermost electrons are further away from the nucleus, leading to an increase in atomic radius. Choice A 'At the top of their group' is incorrect because atomic radius decreases going up within a group. Choice B 'In the middle of their group' is incorrect as the atomic radius generally increases as you go down a group, not in the middle. Choice D 'Along the right-hand side' is incorrect because atomic radius tends to decrease from left to right across a period on the periodic table due to increased nuclear charge and effective nuclear charge.
5. Which intermolecular force is the strongest?
- A. Dipole interactions
- B. Dispersion forces
- C. Hydrogen bonding
- D. Van der Waals forces
Correct answer: C
Rationale: Hydrogen bonding is the strongest intermolecular force due to its specific interaction between a hydrogen atom and a highly electronegative atom like nitrogen, oxygen, or fluorine. This type of bonding results in a very strong attraction between molecules, making it the strongest intermolecular force among the options provided. Dipole interactions (choice A) are weaker than hydrogen bonding as they occur between polar molecules. Dispersion forces (choice B) are the weakest intermolecular forces and are caused by temporary fluctuations in electron distribution. Van der Waals forces (choice D) are a broader term that encompasses dipole interactions and dispersion forces, making them weaker than hydrogen bonding.
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