Nursing Elites

1. Here are the solubilities of four substances at 0°C, in grams of solute per 100 mL of water. If the temperature increases to 20°C, what would you expect to happen to the solubility figures?

• A. Citric acid and potassium phosphate will decrease; nitrogen and oxygen will increase.
• B. Citric acid and potassium phosphate will increase; nitrogen and oxygen will decrease.
• C. All four figures will increase.
• D. All four figures will decrease.

Correct answer: C

Rationale: Solubility generally tends to increase with temperature for most solid solutes in liquid solvents due to higher kinetic energy leading to better solute-solvent interactions. As the temperature increases from 0°C to 20°C, all four solubility figures are expected to increase. Choice A is incorrect because solubility tends to increase with temperature. Choice B is incorrect as well for the same reason. Choice D is incorrect because the solubility of solid solutes typically increases with temperature.

2. If gas A has four times the molar mass of gas B, you would expect it to diffuse through a plug ___________.

• A. at half the rate of gas B
• B. at twice the rate of gas B
• C. at a quarter the rate of gas B
• D. at four times the rate of gas B

Correct answer: A

Rationale: When comparing the diffusion rates of two gases, according to Graham's law of diffusion, the rate of diffusion is inversely proportional to the square root of the molar mass. If gas A has four times the molar mass of gas B, the square root of the molar masses ratio (4:1) is 2. This means that gas A would diffuse through a plug at half the rate of gas B. Therefore, the correct answer is A, at half the rate of gas B. Choices B, C, and D are incorrect because they do not reflect the correct relationship between the molar masses and the rates of diffusion according to Graham's law.

3. You contain two odorous gases in vials with porous plugs. Gas A has twice the mass of Gas B. Which observation is most likely?

• A. You will smell Gas A before you smell Gas B.
• B. You will smell Gas B before you smell Gas A.
• C. You will smell Gas A but not Gas B.
• D. You will smell Gas B but not Gas A.

Correct answer: A

Rationale: The rate of effusion of a gas is inversely proportional to the square root of its molar mass. Since Gas A has twice the mass of Gas B, Gas A will effuse more slowly than Gas B. Therefore, you will likely smell Gas A before you smell Gas B as Gas A will escape and diffuse through the porous plug at a slower rate compared to Gas B. Choice A is correct because Gas A, with its higher molar mass, will take longer to effuse through the porous plug, causing you to smell it first. Choices B, C, and D are incorrect as they do not consider the relationship between molar mass and effusion rate.

4. What is the energy required to remove the outermost electron from an atom called?

• A. covalent bonding
• B. electronegativity
• C. atomic radius
• D. ionization energy

Correct answer: D

Rationale: Ionization energy is the energy needed to remove the outermost electron from an atom, resulting in the formation of a positively charged ion. The higher the ionization energy, the more difficult it is to extract an electron. Electronegativity, however, measures an atom's ability to attract shared electrons in a chemical bond. Atomic radius refers to the distance from the nucleus to the outermost electron. Covalent bonding involves sharing electron pairs between atoms to create a stable bond. Therefore, the correct answer is ionization energy as it specifically relates to the energy needed to remove an electron from an atom.

5. A radioactive isotope has a half-life of 20 years. How many grams of a 6-gram sample will remain after 40 years?

• A. 8
• B. 6
• C. 3
• D. 1.5

Correct answer: C

Rationale: The half-life of a radioactive isotope is the time it takes for half of the original sample to decay. After each half-life period, half of the initial sample remains. In this case, after the first 20 years, half of the 6-gram sample (3 grams) will remain. After another 20 years (total of 40 years), half of the remaining 3 grams will remain, which is 1.5 grams. Therefore, 3 grams will be left after 40 years. Choice A is incorrect as it doesn't consider the concept of half-life and incorrectly suggests an increase in the sample. Choice B is incorrect as it assumes no decay over time. Choice D is incorrect as it miscalculates the remaining amount after two half-life periods.

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