HESI A2
HESI A2 Chemistry
1. Here are the solubilities of four substances at 0°C, in grams of solute per 100 mL of water. If the temperature increases to 20°C, what would you expect to happen to the solubility figures?
- A. Citric acid and potassium phosphate will decrease; nitrogen and oxygen will increase.
- B. Citric acid and potassium phosphate will increase; nitrogen and oxygen will decrease.
- C. All four figures will increase.
- D. All four figures will decrease.
Correct answer: C
Rationale: Solubility generally tends to increase with temperature for most solid solutes in liquid solvents due to higher kinetic energy leading to better solute-solvent interactions. As the temperature increases from 0°C to 20°C, all four solubility figures are expected to increase. Choice A is incorrect because solubility tends to increase with temperature. Choice B is incorrect as well for the same reason. Choice D is incorrect because the solubility of solid solutes typically increases with temperature.
2. Carbon-12 and carbon-14 are isotopes. What do they have in common?
- A. Number of nuclear particles
- B. Number of protons
- C. Number of neutrons
- D. Mass number
Correct answer: C
Rationale: Isotopes are atoms of the same element with the same number of protons (which determines the element) but different numbers of neutrons. Both carbon-12 and carbon-14 have 6 protons (hence they are both carbon atoms) but different numbers of neutrons: carbon-12 has 6 neutrons, while carbon-14 has 8 neutrons. Therefore, the correct answer is the number of neutrons. Choices A, B, and D are incorrect because isotopes may have different numbers of nuclear particles (protons + neutrons), protons, and mass numbers, respectively.
3. To the nearest whole number, what is the mass of one mole of sodium chloride?
- A. 36 g/mol
- B. 43 g/mol
- C. 58 g/mol
- D. 72 g/mol
Correct answer: C
Rationale: The molar mass of sodium chloride (NaCl) is calculated by adding the atomic masses of sodium (Na) and chlorine (Cl). The atomic mass of sodium is approximately 23 g/mol and chlorine is approximately 35.5 g/mol. Adding these two atomic masses gives us a molar mass of approximately 58 g/mol for sodium chloride (NaCl). Therefore, the correct answer is C, 58 g/mol. Choice A (36 g/mol) is incorrect as it does not account for the individual atomic masses of sodium and chlorine. Choice B (43 g/mol) and choice D (72 g/mol) are also incorrect as they do not reflect the accurate molar mass of sodium chloride.
4. What is the pH of acids?
- A. 7.5
- B. < 7
- C. > 7
- D. 7
Correct answer: B
Rationale: The correct answer is B: < 7. Acids have a pH lower than 7, indicating higher acidity. A pH below 7 signifies an acidic solution, with lower values indicating stronger acids. Choice A (7.5) is incorrect as it is greater than 7, which is alkaline. Choice C (> 7) is incorrect as values greater than 7 represent alkaline/basic solutions. Choice D (7) is incorrect because a pH of 7 is neutral, not acidic.
5. Which classification best describes B, Si, As, Te, At, Ge, and Sb that form a staircase pattern on the right side of the periodic table?
- A. Metals
- B. Semimetals
- C. Nonmetals
- D. Ultrametals
Correct answer: B
Rationale: B, Si, As, Te, At, Ge, and Sb are located in a staircase pattern on the periodic table's right side. Elements in this region are known as metalloids or semimetals because they exhibit properties of both metals and nonmetals. They possess characteristics of both metallic and non-metallic elements, making them valuable semiconductors with diverse applications in electronics. Choice A is incorrect because these elements are not considered true metals. Choice C is incorrect as these elements do not display typical nonmetal properties exclusively. Choice D, 'Ultrametals,' is not a recognized classification in chemistry and is therefore incorrect.
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