HESI A2
HESI A2 Chemistry
1. Here are the solubilities of four substances at 0°C, in grams of solute per 100 mL of water. If the temperature increases to 20°C, what would you expect to happen to the solubility figures?
- A. Citric acid and potassium phosphate will decrease; nitrogen and oxygen will increase.
- B. Citric acid and potassium phosphate will increase; nitrogen and oxygen will decrease.
- C. All four figures will increase.
- D. All four figures will decrease.
Correct answer: C
Rationale: Solubility generally tends to increase with temperature for most solid solutes in liquid solvents due to higher kinetic energy leading to better solute-solvent interactions. As the temperature increases from 0°C to 20°C, all four solubility figures are expected to increase. Choice A is incorrect because solubility tends to increase with temperature. Choice B is incorrect as well for the same reason. Choice D is incorrect because the solubility of solid solutes typically increases with temperature.
2. What are the columns of the periodic table called?
- A. Periods
- B. Families
- C. Groups
- D. Rows
Correct answer: C
Rationale: In the periodic table, columns are referred to as groups, not periods, families, or rows. These groups share similar chemical properties due to the arrangement of elements within each group, which is based on the number of valence electrons. The vertical columns help classify elements with similar characteristics. Periods refer to the rows of the periodic table, while families or groups are the vertical columns.
3. What is the name of the group of elements that contains chlorine, fluorine, and iodine?
- A. Alkali metals
- B. Halogens
- C. Transition metals
- D. Noble gases
Correct answer: B
Rationale: The correct answer is 'Halogens.' Halogens are a group of elements that include chlorine, fluorine, and iodine. These elements are part of Group 17 in the periodic table. They share similar properties such as high reactivity and the ability to readily form compounds. Choice A, 'Alkali metals,' is incorrect as alkali metals are found in Group 1 of the periodic table, which includes elements like lithium and sodium. Choice C, 'Transition metals,' is incorrect as transition metals are located in the middle section of the periodic table, not in Group 17. Choice D, 'Noble gases,' is incorrect as noble gases are in Group 18 and include elements like helium and neon, which are chemically inert.
4. Which intermolecular force is the strongest?
- A. Dipole interactions
- B. Dispersion forces
- C. Hydrogen bonding
- D. Van der Waals forces
Correct answer: C
Rationale: Hydrogen bonding is the strongest intermolecular force due to its specific interaction between a hydrogen atom and a highly electronegative atom like nitrogen, oxygen, or fluorine. This type of bonding results in a very strong attraction between molecules, making it the strongest intermolecular force among the options provided. Dipole interactions (choice A) are weaker than hydrogen bonding as they occur between polar molecules. Dispersion forces (choice B) are the weakest intermolecular forces and are caused by temporary fluctuations in electron distribution. Van der Waals forces (choice D) are a broader term that encompasses dipole interactions and dispersion forces, making them weaker than hydrogen bonding.
5. What does a blood sample with a pH of 3 indicate?
- A. It is strongly acidic.
- B. It is strongly basic.
- C. It is weakly acidic.
- D. It is weakly basic.
Correct answer: A
Rationale: A blood pH of 3 is significantly low, indicating a strong acidity level. The normal blood pH range is 7.35 to 7.45; therefore, a pH of 3 is far below the normal range, showing a highly acidic condition in the blood sample. Choice B is incorrect because a pH of 3 is not basic at all. Choice C is incorrect as a pH of 3 is not weakly acidic but strongly acidic. Choice D is wrong as a blood pH of 3 does not indicate a weakly basic condition.
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