HESI A2
HESI A2 Chemistry
1. Here are the solubilities of four substances at 0°C, in grams of solute per 100 mL of water. If the temperature increases to 20°C, what would you expect to happen to the solubility figures?
- A. Citric acid and potassium phosphate will decrease; nitrogen and oxygen will increase.
- B. Citric acid and potassium phosphate will increase; nitrogen and oxygen will decrease.
- C. All four figures will increase.
- D. All four figures will decrease.
Correct answer: C
Rationale: Solubility generally tends to increase with temperature for most solid solutes in liquid solvents due to higher kinetic energy leading to better solute-solvent interactions. As the temperature increases from 0°C to 20°C, all four solubility figures are expected to increase. Choice A is incorrect because solubility tends to increase with temperature. Choice B is incorrect as well for the same reason. Choice D is incorrect because the solubility of solid solutes typically increases with temperature.
2. What are the columns of the periodic table called?
- A. Periods
- B. Families
- C. Groups
- D. Rows
Correct answer: C
Rationale: In the periodic table, columns are referred to as groups, not periods, families, or rows. These groups share similar chemical properties due to the arrangement of elements within each group, which is based on the number of valence electrons. The vertical columns help classify elements with similar characteristics. Periods refer to the rows of the periodic table, while families or groups are the vertical columns.
3. What is the oxidation state of the nitrogen atom in the compound NH3?
- A. -3
- B. -1
- C. +1
- D. +3
Correct answer: B
Rationale: In the compound NH3, nitrogen is bonded to three hydrogen atoms. Hydrogen is always assigned an oxidation state of +1. Since the overall charge of NH3 is zero, the oxidation state of nitrogen must be -1 to balance out the hydrogen's +1 oxidation state. Therefore, the correct oxidation state of the nitrogen atom in NH3 is -1. Choice A (-3) is incorrect because it does not account for the electronegativity of hydrogen. Choice C (+1) and Choice D (+3) are incorrect as the nitrogen atom in NH3 needs to balance the +1 oxidation state of each hydrogen atom, resulting in a total of -3 to maintain the compound's charge neutrality.
4. Which of the following elements does not exist as a diatomic molecule?
- A. boron
- B. fluorine
- C. oxygen
- D. nitrogen
Correct answer: A
Rationale: The correct answer is 'boron.' Diatomic molecules consist of two atoms of the same element bonded together. Boron is an exception and does not exist naturally as a diatomic molecule. On the other hand, fluorine, oxygen, and nitrogen commonly exist as diatomic molecules in their natural states. Fluorine, for example, exists as F2, oxygen exists as O2, and nitrogen exists as N2.
5. What are the three types of radiation?
- A. Alpha, beta, gamma
- B. Alpha, beta, delta
- C. Gamma, delta, epsilon
- D. Beta, gamma, epsilon
Correct answer: A
Rationale: The correct answer is Alpha, beta, gamma. Alpha radiation consists of helium nuclei, beta radiation comprises electrons or positrons, and gamma radiation is high-energy electromagnetic radiation. Choice B, delta, is incorrect as delta is not a type of radiation. Choice C, gamma, delta, epsilon, and Choice D, beta, gamma, epsilon, are incorrect as they do not include the three standard types of radiation.
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