HESI A2
HESI A2 Chemistry
1. Here are the solubilities of four substances at 0°C, in grams of solute per 100 mL of water. If the temperature increases to 20°C, what would you expect to happen to the solubility figures?
- A. Citric acid and potassium phosphate will decrease; nitrogen and oxygen will increase.
- B. Citric acid and potassium phosphate will increase; nitrogen and oxygen will decrease.
- C. All four figures will increase.
- D. All four figures will decrease.
Correct answer: C
Rationale: Solubility generally tends to increase with temperature for most solid solutes in liquid solvents due to higher kinetic energy leading to better solute-solvent interactions. As the temperature increases from 0°C to 20°C, all four solubility figures are expected to increase. Choice A is incorrect because solubility tends to increase with temperature. Choice B is incorrect as well for the same reason. Choice D is incorrect because the solubility of solid solutes typically increases with temperature.
2. What type of intermolecular force is a dipole attraction?
- A. Strong
- B. Weak
- C. Medium
- D. Very strong
Correct answer: B
Rationale: A dipole attraction is considered a weak intermolecular force. It occurs between molecules with permanent dipoles, where the positive end of one molecule is attracted to the negative end of another molecule. While dipole-dipole interactions are stronger than dispersion forces, they are weaker than hydrogen bonding or ion-dipole interactions. Therefore, the correct answer is 'Weak.' Choices A, C, and D are incorrect because dipole attractions are not classified as strong, medium, or very strong intermolecular forces, but rather fall into the category of weak intermolecular forces.
3. What does the mass number minus the atomic number equal?
- A. Number of electrons
- B. Number of neutrons
- C. Number of protons
- D. Number of isotopes
Correct answer: B
Rationale: The mass number of an atom represents the total number of protons and neutrons in its nucleus. The atomic number indicates the number of protons in the nucleus. The difference between the mass number and the atomic number provides the number of neutrons present in the nucleus of an atom. Therefore, mass number minus atomic number equals the number of neutrons. Choice A is incorrect because the number of electrons is not determined by the mass number and atomic number. Choice C is incorrect as it represents the number of protons, not the difference between the mass number and atomic number. Choice D is incorrect as isotopes refer to atoms of the same element with different numbers of neutrons, not the difference between mass number and atomic number.
4. Which particles are emitted during radioactivity?
- A. Electrons
- B. Protons
- C. Radiation
- D. Neutrons
Correct answer: C
Rationale: During radioactivity, radiation is emitted from an unstable nucleus. This radiation can take various forms like alpha particles, beta particles, or gamma rays. These particles or rays are emitted as a result of the unstable nucleus's attempt to achieve a more stable configuration. Therefore, the correct answer is radiation (Choice C). Electrons (Choice A), protons (Choice B), and neutrons (Choice D) are not typically emitted during radioactivity, as the emission is primarily in the form of radiation.
5. In the solid state, you would expect a nonmetal to be _________.
- A. brittle
- B. lustrous
- C. malleable
- D. conductive
Correct answer: A
Rationale: In the solid state, you would expect a nonmetal to be brittle. Nonmetals generally lack the malleability and ductility of metals, which makes them prone to being brittle and easily fractured under stress. This property is due to the lack of metallic bonding in nonmetals, which results in a more rigid and less flexible structure. Choice B, 'lustrous,' is incorrect because nonmetals typically do not exhibit a shiny or reflective surface like metals do. Choice C, 'malleable,' is also incorrect as nonmetals lack the ability to be hammered or rolled into thin sheets like metals. Choice D, 'conductive,' is incorrect since nonmetals are generally poor conductors of electricity compared to metals.
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