HESI A2
HESI A2 Chemistry
1. Here are the solubilities of four substances at 0°C, in grams of solute per 100 mL of water. If the temperature increases to 20°C, what would you expect to happen to the solubility figures?
- A. Citric acid and potassium phosphate will decrease; nitrogen and oxygen will increase.
- B. Citric acid and potassium phosphate will increase; nitrogen and oxygen will decrease.
- C. All four figures will increase.
- D. All four figures will decrease.
Correct answer: C
Rationale: Solubility generally tends to increase with temperature for most solid solutes in liquid solvents due to higher kinetic energy leading to better solute-solvent interactions. As the temperature increases from 0°C to 20°C, all four solubility figures are expected to increase. Choice A is incorrect because solubility tends to increase with temperature. Choice B is incorrect as well for the same reason. Choice D is incorrect because the solubility of solid solutes typically increases with temperature.
2. What is the name of the force that holds ionic compounds together?
- A. Covalent bonds
- B. Ionic bonds
- C. Hydrogen bonds
- D. Metallic bonds
Correct answer: B
Rationale: Ionic bonds are the forces that hold ionic compounds together. In ionic compounds, positively and negatively charged ions are held together by electrostatic forces of attraction, forming a stable structure. Covalent bonds involve the sharing of electrons between atoms, not the transfer of electrons like in ionic bonds. Hydrogen bonds are a type of intermolecular force, not the primary force in holding ionic compounds together. Metallic bonds are found in metals and involve a 'sea of electrons' that hold metal atoms together, different from the electrostatic attraction between ions in ionic compounds.
3. What is the oxidation state of the potassium ion in the compound KCl?
- A. +1
- B. -1
- C. +2
- D. -2
Correct answer: A
Rationale: In the compound KCl (potassium chloride), potassium is in Group 1 of the periodic table, which means it has a valence electron of 1. Chlorine is in Group 17 and gains one electron to achieve a stable electron configuration by forming an ionic bond with potassium. As a result, the potassium ion in KCl has a +1 oxidation state. Therefore, the correct answer is +1. Choices B, C, and D are incorrect as they do not reflect the oxidation state of the potassium ion in KCl.
4. Which number represents the number of protons in an element?
- A. Atomic mass
- B. Mass number
- C. Atomic number
- D. Proton number
Correct answer: C
Rationale: The correct answer is C: Atomic number. The atomic number corresponds to the number of protons in an element. Protons are positively charged subatomic particles found in the nucleus of an atom. Each element has a unique atomic number, which defines its identity based on the number of protons it contains. Choice A, Atomic mass, is incorrect as it refers to the average mass of an atom of an element. Choice B, Mass number, represents the total number of protons and neutrons in an atom's nucleus. Choice D, Proton number, is not a commonly used term in chemistry to indicate the number of protons.
5. Which of the following substances is a base?
- A. Water
- B. Sodium chloride
- C. Ammonia
- D. Salt
Correct answer: C
Rationale: The correct answer is 'Ammonia' (Choice C) as it is a common example of a base. Bases are substances that release hydroxide ions (OH-) in aqueous solutions, helping to increase the pH level. Ammonia is a weak base that can accept a proton (H+) to form ammonium hydroxide. In contrast, water (Choice A), sodium chloride (Choice B), and salt (Choice D) are not bases; water is neutral, while sodium chloride and salt are neutral compounds composed of a cation and an anion.
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