HESI A2
HESI A2 Chemistry
1. Here are the solubilities of four substances at 0°C, in grams of solute per 100 mL of water. If the temperature increases to 20°C, what would you expect to happen to the solubility figures?
- A. Citric acid and potassium phosphate will decrease; nitrogen and oxygen will increase.
- B. Citric acid and potassium phosphate will increase; nitrogen and oxygen will decrease.
- C. All four figures will increase.
- D. All four figures will decrease.
Correct answer: C
Rationale: Solubility generally tends to increase with temperature for most solid solutes in liquid solvents due to higher kinetic energy leading to better solute-solvent interactions. As the temperature increases from 0°C to 20°C, all four solubility figures are expected to increase. Choice A is incorrect because solubility tends to increase with temperature. Choice B is incorrect as well for the same reason. Choice D is incorrect because the solubility of solid solutes typically increases with temperature.
2. What is the charge of noble gases?
- A. -1
- B. 0
- C. 1
- D. 2
Correct answer: B
Rationale: The correct answer is B: 0. Noble gases have a charge of 0 because they have full valence shells and are inert. This makes them stable and unreactive, resulting in a charge of 0 as they do not readily gain or lose electrons. Choices A, C, and D are incorrect because noble gases do not typically form ions by gaining or losing electrons, so they do not carry a charge of -1, 1, or 2.
3. Where would you expect tap water to fall on the pH scale?
- A. Between 1 and 3
- B. Between 4 and 6
- C. Between 6 and 8
- D. Between 8 and 10
Correct answer: C
Rationale: Tap water typically falls within the pH range of 6 to 8, making it slightly acidic to neutral. Most municipal water systems aim to provide water that is safe for consumption and falls within this pH range. A pH level of 7 is considered neutral, so tap water may vary slightly on either side of this number but typically remains within the 6 to 8 range to ensure it is safe for consumption. Choices A, B, and D are incorrect because tap water is not expected to have a pH as low as 1-3 (highly acidic) or as high as 8-10 (alkaline); it usually falls within the slightly acidic to neutral range, hence falling between 6 and 8 on the pH scale.
4. Which element has the highest electronegativity?
- A. Fluorine
- B. Chlorine
- C. Nitrogen
- D. Oxygen
Correct answer: A
Rationale: Fluorine has the highest electronegativity among the elements listed. Electronegativity is a measure of an atom's ability to attract and hold onto electrons in a chemical bond. Fluorine, being the most electronegative element on the periodic table, has the strongest ability to attract electrons towards itself compared to chlorine, nitrogen, and oxygen. Therefore, fluorine is the correct answer. Chlorine, nitrogen, and oxygen have lower electronegativities compared to fluorine, making them incorrect choices for the element with the highest electronegativity.
5. What is atomic mass?
- A. Number of protons in an atom
- B. Sum of protons and neutrons
- C. Number of neutrons in an atom
- D. Average weight of an element
Correct answer: B
Rationale: Atomic mass, also known as atomic weight, is the sum of the number of protons and neutrons in an atom. It represents the average mass of an atom of an element, taking into account the different isotopes and their relative abundance. Neutrons contribute to the atomic mass alongside protons, while the number of neutrons alone is not the definition of atomic mass. Choice A is incorrect because it refers only to the number of protons, not the complete atomic mass. Choice C is incorrect as it focuses solely on the number of neutrons, excluding the contribution of protons. Choice D is incorrect as it mentions the 'average weight of an element,' which is related to atomic mass but does not encapsulate the specific definition of atomic mass as the sum of protons and neutrons.
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