HESI A2
HESI A2 Chemistry
1. Here are the solubilities of four substances at 0°C, in grams of solute per 100 mL of water. If the temperature increases to 20°C, what would you expect to happen to the solubility figures?
- A. Citric acid and potassium phosphate will decrease; nitrogen and oxygen will increase.
- B. Citric acid and potassium phosphate will increase; nitrogen and oxygen will decrease.
- C. All four figures will increase.
- D. All four figures will decrease.
Correct answer: C
Rationale: Solubility generally tends to increase with temperature for most solid solutes in liquid solvents due to higher kinetic energy leading to better solute-solvent interactions. As the temperature increases from 0°C to 20°C, all four solubility figures are expected to increase. Choice A is incorrect because solubility tends to increase with temperature. Choice B is incorrect as well for the same reason. Choice D is incorrect because the solubility of solid solutes typically increases with temperature.
2. What is the name of the process by which a gas turns into a liquid?
- A. Sublimation
- B. Condensation
- C. Evaporation
- D. Deposition
Correct answer: B
Rationale: The correct answer is B: Condensation. Condensation is the process where gas transforms into a liquid. When gas cools down, it loses energy and its particles come closer, leading to the formation of liquid droplets. Sublimation is the direct transition from solid to gas without passing through the liquid state. Evaporation is the process of liquid turning into a gas, and deposition is the transition of gas directly into a solid. Therefore, choices A, C, and D are incorrect as they describe different phase transitions.
3. How does increasing the concentration of reactants affect a chemical reaction?
- A. Decreases the reaction rate
- B. Increases the reaction rate
- C. Stops the reaction
- D. Has no effect
Correct answer: B
Rationale: Increasing the concentration of reactants leads to more reactant particles being available, which, in turn, increases the likelihood of successful collisions between particles. This higher frequency of collisions results in a higher reaction rate. Therefore, option B, 'Increases the reaction rate,' is the correct answer. Choice A, 'Decreases the reaction rate,' is incorrect because higher reactant concentration usually speeds up the reaction. Choice C, 'Stops the reaction,' is incorrect as increasing concentration promotes more collisions, enhancing the reaction. Choice D, 'Has no effect,' is incorrect because changing reactant concentration directly impacts the reaction rate in most cases.
4. A radioactive isotope has a half-life of 20 years. How many grams of a 6-gram sample will remain after 40 years?
- A. 8
- B. 6
- C. 3
- D. 1.5
Correct answer: C
Rationale: The half-life of a radioactive isotope is the time it takes for half of the original sample to decay. After each half-life period, half of the initial sample remains. In this case, after the first 20 years, half of the 6-gram sample (3 grams) will remain. After another 20 years (total of 40 years), half of the remaining 3 grams will remain, which is 1.5 grams. Therefore, 3 grams will be left after 40 years. Choice A is incorrect as it doesn't consider the concept of half-life and incorrectly suggests an increase in the sample. Choice B is incorrect as it assumes no decay over time. Choice D is incorrect as it miscalculates the remaining amount after two half-life periods.
5. Which statement is true of a saturated solution?
- A. It has more solute than can dissolve in the solvent.
- B. It has less solute that can dissolve in the solvent.
- C. It has the maximum concentration of the solute dissolved in the solvent.
- D. It contains a precipitate that lowers the concentration of the solute in the solvent.
Correct answer: C
Rationale: A saturated solution contains the maximum concentration of solute that can be dissolved in a specific amount of solvent at a particular temperature. Once a solution is saturated, adding more solute will not increase its concentration since the excess solute will not dissolve and will instead form a precipitate, indicating that the solution is at its maximum capacity. Choices A, B, and D are incorrect because a saturated solution has reached its limit in dissolving solute, so it cannot contain more solute than it can dissolve (choice A), less solute than it can dissolve (choice B), or a precipitate that lowers the concentration of the solute in the solvent (choice D).
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