HESI A2
HESI A2 Chemistry
1. Here are the solubilities of four substances at 0°C, in grams of solute per 100 mL of water. If the temperature increases to 20°C, what would you expect to happen to the solubility figures?
- A. Citric acid and potassium phosphate will decrease; nitrogen and oxygen will increase.
- B. Citric acid and potassium phosphate will increase; nitrogen and oxygen will decrease.
- C. All four figures will increase.
- D. All four figures will decrease.
Correct answer: C
Rationale: Solubility generally tends to increase with temperature for most solid solutes in liquid solvents due to higher kinetic energy leading to better solute-solvent interactions. As the temperature increases from 0°C to 20°C, all four solubility figures are expected to increase. Choice A is incorrect because solubility tends to increase with temperature. Choice B is incorrect as well for the same reason. Choice D is incorrect because the solubility of solid solutes typically increases with temperature.
2. Which of the following factors would not affect rates of reaction?
- A. Temperature
- B. Surface area
- C. Pressure
- D. Time
Correct answer: D
Rationale: Time would not directly affect rates of reaction. The rate of a chemical reaction is determined by factors that affect the frequency of successful collisions between reactant molecules, leading to a reaction. Temperature, surface area, and pressure can influence reaction rates by impacting the kinetic energy of molecules, the exposed surface for collisions, and the concentration of reactants, respectively. However, time, in the context of this question, does not alter the rate of reaction but may affect the extent of the reaction or the amount of product formed over time.
3. What is the number of protons in the atomic nucleus of an alkali metal?
- A. 9
- B. 10
- C. 11
- D. 12
Correct answer: C
Rationale: The number of protons in the atomic nucleus of an alkali metal is 11. Alkali metals, belonging to group 1 of the periodic table, have 1 electron in their outer shell, which corresponds to 1 proton in their nucleus. Therefore, the correct answer is option C: 11. Choice A (9) is incorrect because it does not match the number of protons in an alkali metal. Choice B (10) is incorrect as it is also not the correct number of protons for an alkali metal. Choice D (12) is incorrect as it is not the typical number of protons found in the nucleus of an alkali metal.
4. What is the correct formula for sodium nitrate?
- A. NaNO
- B. Na NO
- C. NaNO₃
- D. Na NO₂
Correct answer: C
Rationale: The correct formula for sodium nitrate is NaNO₃. In this formula, 'Na' represents sodium, 'N' represents nitrogen, and 'O₃' represents three oxygen atoms. Sodium nitrate consists of one sodium ion (Na⁺) and one nitrate ion (NO₃⁻), which means the correct formula is NaNO₃. Choice A (NaNO) is incorrect as it lacks the subscript indicating the presence of three oxygen atoms. Choice B (Na NO) is incorrect as it includes a space between 'Na' and 'NO', which is not part of the standard chemical formula notation. Choice D (Na NO₂) is incorrect as it indicates a different compound with a nitrite ion (NO₂⁻) instead of nitrate ion.
5. In the periodic table, which group contains the alkali metals?
- A. Group 7
- B. Group 1
- C. Group 2
- D. Group 3
Correct answer: B
Rationale: The correct answer is Group 1. Alkali metals are found in Group 1 of the periodic table, which includes elements such as lithium, sodium, and potassium. These elements are known for their high reactivity and tendency to form alkaline solutions when they react with water. Therefore, Group 1 is specifically designated as the group containing alkali metals. Choice A (Group 7) is incorrect as Group 7 contains the halogens. Choice C (Group 2) is incorrect as Group 2 contains the alkaline earth metals. Choice D (Group 3) is incorrect as Group 3 contains the scandium group of elements.
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