HESI A2
HESI A2 Chemistry
1. Here are the solubilities of four substances at 0°C, in grams of solute per 100 mL of water. If the temperature increases to 20°C, what would you expect to happen to the solubility figures?
- A. Citric acid and potassium phosphate will decrease; nitrogen and oxygen will increase.
- B. Citric acid and potassium phosphate will increase; nitrogen and oxygen will decrease.
- C. All four figures will increase.
- D. All four figures will decrease.
Correct answer: C
Rationale: Solubility generally tends to increase with temperature for most solid solutes in liquid solvents due to higher kinetic energy leading to better solute-solvent interactions. As the temperature increases from 0°C to 20°C, all four solubility figures are expected to increase. Choice A is incorrect because solubility tends to increase with temperature. Choice B is incorrect as well for the same reason. Choice D is incorrect because the solubility of solid solutes typically increases with temperature.
2. What can stop the penetration of beta radiation particles?
- A. Plastic
- B. Glass
- C. Aluminum foil
- D. Concrete
Correct answer: C
Rationale: Beta radiation particles are high-energy, fast-moving electrons or positrons. Aluminum foil is effective in stopping beta radiation due to its ability to absorb and block these particles. When beta particles interact with the aluminum foil, they lose energy and are absorbed, preventing their penetration. Plastic and glass are not as effective as aluminum foil in stopping beta radiation. While concrete provides some shielding against beta particles, aluminum foil is a more suitable material for this purpose as it offers better absorption and blocking capabilities.
3. What charge do Group IIA elements typically have?
- A. 1
- B. +2
- C. -3
- D. 0
Correct answer: B
Rationale: Group IIA elements belong to the alkaline earth metals group in the periodic table. These elements typically have a charge of +2 because they readily lose two electrons to achieve a stable electron configuration. Therefore, the correct answer is B - +2. Choice A (1) is incorrect because Group IIA elements lose two electrons, not one. Choice C (-3) is incorrect because Group IIA elements do not gain electrons to have a negative charge. Choice D (0) is incorrect because Group IIA elements do lose electrons and have a positive charge, not a neutral charge.
4. What type of reaction involves atoms attempting to achieve stable electron configurations?
- A. Chemical
- B. Nuclear
- C. Physical
- D. Mechanical
Correct answer: A
Rationale: In a chemical reaction, atoms interact to achieve stable electron configurations through the formation of new chemical bonds or the breaking of existing ones. This process aims to reach a more stable state by filling or emptying electron orbitals, leading to the formation of new substances with more stable configurations. Choice B, nuclear reactions, involve changes in the atomic nucleus rather than electron configurations. Choice C, physical reactions, involve changes in physical state or appearance without changing the chemical makeup. Choice D, mechanical reactions, do not involve the rearrangement of electrons to achieve stable configurations.
5. When an acid is added to a base, water and a salt form. What kinds of bonds form in these two compounds?
- A. Liquid and metallic
- B. Polar and nonpolar covalent
- C. Polar covalent and ionic
- D. Ionic only
Correct answer: C
Rationale: In water, the bond formed between the oxygen atom and the hydrogen atoms is a polar covalent bond. The oxygen atom attracts the shared electrons more strongly, creating a partial negative charge on the oxygen and a partial positive charge on the hydrogen atoms. In the salt formed, the bond between the metal cation and the nonmetal anion is predominantly an ionic bond. The metal cation donates electrons to the nonmetal anion, resulting in the formation of oppositely charged ions that are held together by electrostatic attractions. Choices A and B are incorrect because water and salts do not form bonds that are liquid and metallic, or polar and nonpolar covalent. Choice D is incorrect as it oversimplifies the types of bonds present in water and salts, failing to differentiate between the covalent bond in water and the ionic bond in the salt.
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