HESI A2
HESI A2 Chemistry
1. Here are the solubilities of four substances at 0°C, in grams of solute per 100 mL of water. If the temperature increases to 20°C, what would you expect to happen to the solubility figures?
- A. Citric acid and potassium phosphate will decrease; nitrogen and oxygen will increase.
- B. Citric acid and potassium phosphate will increase; nitrogen and oxygen will decrease.
- C. All four figures will increase.
- D. All four figures will decrease.
Correct answer: C
Rationale: Solubility generally tends to increase with temperature for most solid solutes in liquid solvents due to higher kinetic energy leading to better solute-solvent interactions. As the temperature increases from 0°C to 20°C, all four solubility figures are expected to increase. Choice A is incorrect because solubility tends to increase with temperature. Choice B is incorrect as well for the same reason. Choice D is incorrect because the solubility of solid solutes typically increases with temperature.
2. What term refers to the average of the masses of each of its isotopes as they occur in nature?
- A. Atomic number
- B. Mass number
- C. Atomic mass
- D. Neutron number
Correct answer: C
Rationale: The correct answer is atomic mass. Atomic mass is the weighted average of the masses of an element's isotopes. It takes into account the abundance of each isotope in nature to provide a more accurate representation of the element's overall mass. Choice A, atomic number, represents the number of protons in an atom. Choice B, mass number, refers to the total number of protons and neutrons in an atom's nucleus. Choice D, neutron number, specifically focuses on the count of neutrons in an atom's nucleus. These choices do not directly relate to the average mass of isotopes as asked in the question.
3. When an acid is added to a base, water and a salt form. What kinds of bonds form in these two compounds?
- A. Liquid and metallic
- B. Polar and nonpolar covalent
- C. Polar covalent and ionic
- D. Ionic only
Correct answer: C
Rationale: In water, the bond formed between the oxygen atom and the hydrogen atoms is a polar covalent bond. The oxygen atom attracts the shared electrons more strongly, creating a partial negative charge on the oxygen and a partial positive charge on the hydrogen atoms. In the salt formed, the bond between the metal cation and the nonmetal anion is predominantly an ionic bond. The metal cation donates electrons to the nonmetal anion, resulting in the formation of oppositely charged ions that are held together by electrostatic attractions. Choices A and B are incorrect because water and salts do not form bonds that are liquid and metallic, or polar and nonpolar covalent. Choice D is incorrect as it oversimplifies the types of bonds present in water and salts, failing to differentiate between the covalent bond in water and the ionic bond in the salt.
4. Balance this equation: Fe + Cl2 → FeCl3
- A. 2Fe + 2Cl2 → 2FeCl3
- B. 2Fe + 3Cl2 → 2FeCl3
- C. 3Fe + 2Cl2 → 3FeCl3
- D. 3Fe + 3Cl2 → 6FeCl3
Correct answer: B
Rationale: In the given equation, Fe combines with Cl to form FeCl3. To balance the equation, we need to have the same number of each element on both sides. Since Cl is represented as Cl2 in the equation, we need 3 Cl2 molecules to balance Fe, resulting in 2Fe + 3Cl2 → 2FeCl3. Choice A is incorrect because it only balances Fe but not Cl2. Choice C is incorrect as it balances Fe but not Cl2. Choice D is incorrect as it balances Fe but overbalances Cl2.
5. What is the name of the group of elements that contains chlorine, fluorine, and iodine?
- A. Alkali metals
- B. Halogens
- C. Transition metals
- D. Noble gases
Correct answer: B
Rationale: The correct answer is 'Halogens.' Halogens are a group of elements that include chlorine, fluorine, and iodine. These elements are part of Group 17 in the periodic table. They share similar properties such as high reactivity and the ability to readily form compounds. Choice A, 'Alkali metals,' is incorrect as alkali metals are found in Group 1 of the periodic table, which includes elements like lithium and sodium. Choice C, 'Transition metals,' is incorrect as transition metals are located in the middle section of the periodic table, not in Group 17. Choice D, 'Noble gases,' is incorrect as noble gases are in Group 18 and include elements like helium and neon, which are chemically inert.
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