HESI A2
HESI A2 Chemistry
1. Here are the solubilities of four substances at 0°C, in grams of solute per 100 mL of water. If the temperature increases to 20°C, what would you expect to happen to the solubility figures?
- A. Citric acid and potassium phosphate will decrease; nitrogen and oxygen will increase.
- B. Citric acid and potassium phosphate will increase; nitrogen and oxygen will decrease.
- C. All four figures will increase.
- D. All four figures will decrease.
Correct answer: C
Rationale: Solubility generally tends to increase with temperature for most solid solutes in liquid solvents due to higher kinetic energy leading to better solute-solvent interactions. As the temperature increases from 0°C to 20°C, all four solubility figures are expected to increase. Choice A is incorrect because solubility tends to increase with temperature. Choice B is incorrect as well for the same reason. Choice D is incorrect because the solubility of solid solutes typically increases with temperature.
2. How many neutrons are in an atom of uranium-235?
- A. 92
- B. 125
- C. 143
- D. 235
Correct answer: A
Rationale: The correct answer is A: '92'. To determine the number of neutrons in an atom, you subtract the atomic number (number of protons) from the atomic mass number. For uranium-235, the atomic number is 92, and the atomic mass number is 235. Subtracting 92 from 235 gives us 143 neutrons in an atom of uranium-235. Therefore, options B, C, and D are incorrect as they do not represent the correct number of neutrons in an atom of uranium-235.
3. If gas A has four times the molar mass of gas B, you would expect it to diffuse through a plug ___________.
- A. at half the rate of gas B
- B. at twice the rate of gas B
- C. at a quarter the rate of gas B
- D. at four times the rate of gas B
Correct answer: A
Rationale: When comparing the diffusion rates of two gases, according to Graham's law of diffusion, the rate of diffusion is inversely proportional to the square root of the molar mass. If gas A has four times the molar mass of gas B, the square root of the molar masses ratio (4:1) is 2. This means that gas A would diffuse through a plug at half the rate of gas B. Therefore, the correct answer is A, at half the rate of gas B. Choices B, C, and D are incorrect because they do not reflect the correct relationship between the molar masses and the rates of diffusion according to Graham's law.
4. If electrons are shared equally in a covalent bond, the bond is classified as what?
- A. Polar
- B. Non-polar
- C. Ionic
- D. Hydrogen
Correct answer: B
Rationale: The correct answer is B: Non-polar. In a non-polar covalent bond, electrons are shared equally between the atoms involved, leading to a balanced distribution of charge and no significant difference in electronegativity between the atoms. This equal sharing results in a non-polar bond. Choices A, C, and D are incorrect because a polar bond involves an unequal sharing of electrons, an ionic bond is formed by the transfer of electrons, and a hydrogen bond is a specific type of non-covalent bond.
5. Identify the type of reaction shown: 8Fe + S → 8FeS
- A. Single displacement
- B. Double displacement
- C. Synthesis
- D. Acid-base
Correct answer: C
Rationale: The reaction shown (8Fe + S → 8FeS) is a synthesis reaction. In a synthesis reaction, two or more substances combine to form a single compound. In this case, iron (Fe) and sulfur (S) combine to form iron sulfide (FeS). The key characteristic of a synthesis reaction is the formation of a single product from multiple reactants, which aligns with the given chemical equation. Choice A, single displacement, involves an element displacing another in a compound, which is not the case here. Choice B, double displacement, involves the exchange of ions between two compounds, which is also not happening in this reaction. Choice D, acid-base, refers to reactions between an acid and a base to form salt and water, which is not the case in the given equation.
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