HESI A2
HESI A2 Chemistry
1. You contain two odorous gases in vials with porous plugs. Gas A has twice the mass of Gas B. Which observation is most likely?
- A. You will smell Gas A before you smell Gas B.
- B. You will smell Gas B before you smell Gas A.
- C. You will smell Gas A but not Gas B.
- D. You will smell Gas B but not Gas A.
Correct answer: A
Rationale: The rate of effusion of a gas is inversely proportional to the square root of its molar mass. Since Gas A has twice the mass of Gas B, Gas A will effuse more slowly than Gas B. Therefore, you will likely smell Gas A before you smell Gas B as Gas A will escape and diffuse through the porous plug at a slower rate compared to Gas B. Choice A is correct because Gas A, with its higher molar mass, will take longer to effuse through the porous plug, causing you to smell it first. Choices B, C, and D are incorrect as they do not consider the relationship between molar mass and effusion rate.
2. In what type of covalent compounds are dispersion forces typically found?
- A. Polar
- B. Non-polar
- C. Ionic
- D. Hydrogen
Correct answer: B
Rationale: Dispersion forces, also known as London dispersion forces, are the weakest intermolecular forces that occur in non-polar covalent compounds. These forces result from temporary shifts in electron density within molecules, creating temporary dipoles. As a result, non-polar molecules, which lack a permanent dipole moment, can experience these dispersion forces. Polar compounds exhibit stronger intermolecular forces such as dipole-dipole interactions or hydrogen bonding, while ionic compounds involve electrostatic interactions between ions. Therefore, the correct answer is non-polar (choice B). Choices A, C, and D are incorrect because dispersion forces are typically found in non-polar covalent compounds, not polar, ionic, or hydrogen-bonded compounds.
3. Which element would you expect to be least reactive?
- A. Li
- B. Cr
- C. Nd
- D. Xe
Correct answer: D
Rationale: Xenon (Xe) is a noble gas located in Group 18 of the periodic table. Noble gases are known for their stable and unreactive nature due to having a full outer shell of electrons. Therefore, xenon would be expected to be the least reactive among the given elements. Choice A (Li) is a metal in Group 1 of the periodic table, which tends to be reactive, especially with water. Choice B (Cr) is a transition metal known for its reactivity in some forms. Choice C (Nd) is a rare earth element, which can exhibit varying reactivity depending on the compound or environment.
4. What is the oxidation state of the chlorine atom in the compound HCl?
- A. +1
- B. -1
- C. +2
- D. -2
Correct answer: B
Rationale: In the compound HCl (hydrochloric acid), the hydrogen atom has an oxidation state of +1 based on the rules of assigning oxidation states. Since the overall compound is neutral, the oxidation state of chlorine must be -1 to balance the charge. Chlorine typically has an oxidation state of -1 in binary compounds with nonmetals, such as HCl. Therefore, the correct answer is -1. Choices A, C, and D are incorrect as the oxidation state of chlorine in HCl is -1, not +1, +2, or -2.
5. If electrons are shared equally in a covalent bond, the bond is classified as what?
- A. Polar
- B. Non-polar
- C. Ionic
- D. Hydrogen
Correct answer: B
Rationale: The correct answer is B: Non-polar. In a non-polar covalent bond, electrons are shared equally between the atoms involved, leading to a balanced distribution of charge and no significant difference in electronegativity between the atoms. This equal sharing results in a non-polar bond. Choices A, C, and D are incorrect because a polar bond involves an unequal sharing of electrons, an ionic bond is formed by the transfer of electrons, and a hydrogen bond is a specific type of non-covalent bond.
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