HESI A2
HESI A2 Chemistry
1. You contain two odorous gases in vials with porous plugs. Gas A has twice the mass of Gas B. Which observation is most likely?
- A. You will smell Gas A before you smell Gas B.
- B. You will smell Gas B before you smell Gas A.
- C. You will smell Gas A but not Gas B.
- D. You will smell Gas B but not Gas A.
Correct answer: A
Rationale: The rate of effusion of a gas is inversely proportional to the square root of its molar mass. Since Gas A has twice the mass of Gas B, Gas A will effuse more slowly than Gas B. Therefore, you will likely smell Gas A before you smell Gas B as Gas A will escape and diffuse through the porous plug at a slower rate compared to Gas B. Choice A is correct because Gas A, with its higher molar mass, will take longer to effuse through the porous plug, causing you to smell it first. Choices B, C, and D are incorrect as they do not consider the relationship between molar mass and effusion rate.
2. How many electrons are shared in a single covalent bond?
- A. 1
- B. 2
- C. 3
- D. 4
Correct answer: B
Rationale: The correct answer is B: '2'. In a single covalent bond, two electrons are shared between two atoms. Each atom contributes one electron to form the bond, resulting in the sharing of a total of two electrons. Choice A is incorrect because a single covalent bond involves the sharing of two electrons, not one. Choices C and D are incorrect as they do not represent the correct number of electrons shared in a single covalent bond.
3. What is a balanced equation?
- A. A description where reactants and products are not equal
- B. An equation where the number of each type of atom is the same on both sides
- C. A chemical formula showing only reactants
- D. An equation without coefficients
Correct answer: B
Rationale: A balanced equation is one where the number of each type of atom is the same on both sides, fulfilling the law of conservation of mass. This principle ensures that the total number of atoms of each element is equal in both reactants and products, signifying that no atoms are created or destroyed, but rather rearranged. Choice A is incorrect because a balanced equation has equal numbers of atoms in the reactants and products. Choice C is incorrect as a balanced equation includes both reactants and products. Choice D is incorrect because coefficients are essential in balancing equations by adjusting the number of atoms present.
4. What is the name of the device that separates gaseous ions by their mass-to-charge ratio?
- A. mass spectrometer
- B. interferometer
- C. magnetometer
- D. capacitance meter
Correct answer: A
Rationale: A mass spectrometer is a device specifically designed to separate gaseous ions based on their mass-to-charge ratio. This separation process involves ionization, acceleration of the sample, and the deflection of ions in a magnetic field according to their mass-to-charge ratio. The other options, 'interferometer,' 'magnetometer,' and 'capacitance meter,' do not perform the specific function of separating gaseous ions based on their mass-to-charge ratio, making them incorrect choices.
5. Which of the following factors would not affect rates of reaction?
- A. Temperature
- B. Surface area
- C. Pressure
- D. Time
Correct answer: D
Rationale: Time would not directly affect rates of reaction. The rate of a chemical reaction is determined by factors that affect the frequency of successful collisions between reactant molecules, leading to a reaction. Temperature, surface area, and pressure can influence reaction rates by impacting the kinetic energy of molecules, the exposed surface for collisions, and the concentration of reactants, respectively. However, time, in the context of this question, does not alter the rate of reaction but may affect the extent of the reaction or the amount of product formed over time.
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