HESI A2
HESI A2 Chemistry Practice Questions
1. Which one is not a hydrocarbon?
- A. Methane (CH4)
- B. Pyridine (C5H5N)
- C. Ethane (C2H6)
- D. Propane (C3H8)
Correct answer: B
Rationale: The correct answer is B, Pyridine (C5H5N). Pyridine is not a hydrocarbon because it contains nitrogen (N) in its molecular structure, in addition to carbon (C) and hydrogen (H) atoms. Hydrocarbons consist solely of carbon and hydrogen atoms. Methane (CH4), ethane (C2H6), and propane (C3H8) are all examples of hydrocarbons as they only contain carbon and hydrogen atoms, making them organic compounds known for their combustion properties.
2. Which state of matter has a definite volume but takes the shape of its container?
- A. Gas
- B. Liquid
- C. Solid
- D. Plasma
Correct answer: B
Rationale: The state of matter that has a definite volume but takes the shape of its container is a 'Liquid.' Liquids have a fixed volume but can change their shape to fit the container they are in. This property distinguishes liquids from solids, which have both a definite shape and volume, and gases, which do not have a fixed volume or shape. Therefore, the correct answer is 'Liquid.' Choice A, 'Gas,' is incorrect because gases do not have a definite volume or shape. Choice C, 'Solid,' is incorrect as solids have a definite shape and volume. Choice D, 'Plasma,' is incorrect because plasma is a state of matter where atoms have been ionized and do not have a fixed volume or shape.
3. What are the three types of intermolecular forces?
- A. Ionic, covalent, hydrogen
- B. Hydrogen bonding, dipole interactions, dispersion forces
- C. Van der Waals, ionic, covalent
- D. Hydrogen, Van der Waals, dispersion forces
Correct answer: B
Rationale: The three types of intermolecular forces are hydrogen bonding, dipole interactions, and dispersion forces. Option A includes ionic and covalent bonds, which are intramolecular forces, not intermolecular. Option C includes van der Waals forces, which encompass dipole interactions and dispersion forces, but also includes ionic and covalent bonds. Option D is close but misses dipole interactions, which are distinct from hydrogen bonding and dispersion forces. Therefore, option B is the correct choice as it includes the three specific types of intermolecular forces.
4. Which of these types of intermolecular force is the strongest?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: D
Rationale: Hydrogen bonding is the strongest type of intermolecular force among the options provided. It occurs when a hydrogen atom is covalently bonded to a highly electronegative atom (such as nitrogen, oxygen, or fluorine) and forms a strong electrostatic attraction with an unshared pair of electrons on another electronegative atom. This type of bond is stronger than dipole-dipole interactions, London dispersion forces, and Keesom interactions due to the significant electronegativity difference between the hydrogen and the electronegative atom involved in the bond. The presence of hydrogen bonding contributes to unique properties in substances, such as high boiling and melting points, making it a crucial force in various biological and chemical processes.
5. Here are the solubilities of four substances at 0°C, in grams of solute per 100 mL of water. If the temperature increases to 20°C, what would you expect to happen to the solubility figures?
- A. Citric acid and potassium phosphate will decrease; nitrogen and oxygen will increase.
- B. Citric acid and potassium phosphate will increase; nitrogen and oxygen will decrease.
- C. All four figures will increase.
- D. All four figures will decrease.
Correct answer: C
Rationale: Solubility generally tends to increase with temperature for most solid solutes in liquid solvents due to higher kinetic energy leading to better solute-solvent interactions. As the temperature increases from 0°C to 20°C, all four solubility figures are expected to increase. Choice A is incorrect because solubility tends to increase with temperature. Choice B is incorrect as well for the same reason. Choice D is incorrect because the solubility of solid solutes typically increases with temperature.
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