HESI A2
HESI A2 Chemistry Practice Questions
1. Which of these types of intermolecular force is weakest?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Hydrogen bonding
- D. Ionic bonding
Correct answer: B
Rationale: The correct answer is B, London dispersion force. London dispersion forces are the weakest type of intermolecular force among the options provided. These forces arise from temporary fluctuations in electron distribution within molecules, leading to temporary dipoles. London dispersion forces are present in all molecules and are generally weaker than dipole-dipole interactions, hydrogen bonding, and ionic bonding. Dipole-dipole interactions are stronger than London dispersion forces as they involve permanent dipoles in molecules. Hydrogen bonding is stronger than both London dispersion and dipole-dipole interactions as it is a special type of dipole-dipole interaction that occurs when hydrogen is bonded to highly electronegative atoms like oxygen or nitrogen. Ionic bonding is the strongest type of intermolecular force among the options, but it is not the correct answer for the weakest type of force.
2. A chemist takes 100 mL of a 40 g NaCl solution and dilutes it to 1L. What is the concentration (molarity) of the new solution?
- A. 0.04 M NaCl
- B. 0.25 M NaCl
- C. 0.40 M NaCl
- D. 2.5 M NaCl
Correct answer: C
Rationale: Initially, the chemist has 40 g of NaCl in 100 mL of solution. To find the initial molarity, we need to calculate the number of moles of NaCl using the molar mass of NaCl (58.44 g/mol). After dilution to 1 L, the molarity of the new solution can be calculated by dividing the moles of NaCl by the total volume in liters. Therefore, the concentration (molarity) of the new solution is 0.40 M NaCl. Choice A (0.04 M NaCl) is incorrect because it doesn't consider the correct molar concentration after dilution. Choice B (0.25 M NaCl) is incorrect as it also doesn't account for the correct molar concentration post-dilution. Choice D (2.5 M NaCl) is incorrect as it is too concentrated given the initial amount of NaCl and the dilution factor.
3. What are the three types of radiation?
- A. Alpha, beta, gamma
- B. Alpha, beta, delta
- C. Gamma, delta, epsilon
- D. Beta, gamma, epsilon
Correct answer: A
Rationale: The correct answer is Alpha, beta, gamma. Alpha radiation consists of helium nuclei, beta radiation comprises electrons or positrons, and gamma radiation is high-energy electromagnetic radiation. Choice B, delta, is incorrect as delta is not a type of radiation. Choice C, gamma, delta, epsilon, and Choice D, beta, gamma, epsilon, are incorrect as they do not include the three standard types of radiation.
4. Which of the following is a characteristic of a chemical change?
- A. Change in shape
- B. Production of gas
- C. Melting
- D. Freezing
Correct answer: B
Rationale: The production of gas is a characteristic of a chemical change. During a chemical change, new substances are formed, often with the release or absorption of energy. The production of gas is a significant indicator of a chemical change because it indicates the formation of new compounds through chemical reactions. Choices A, C, and D are not characteristics of chemical changes. Changes in shape, melting, and freezing are physical changes where the substance's identity remains the same, unlike in chemical changes where new substances with different properties are formed.
5. What type of bond is an electrostatic attraction between two oppositely charged ions?
- A. Covalent
- B. Metallic
- C. Ionic
- D. Hydrogen
Correct answer: C
Rationale: An ionic bond forms when one atom transfers electrons to another, resulting in the formation of positively and negatively charged ions. The attraction between these oppositely charged ions creates an electrostatic bond, known as an ionic bond. Choice A, covalent bonds, involve the sharing of electrons, not the transfer. Choice B, metallic bonds, occur between metal atoms and involve a 'sea of electrons' that are delocalized. Choice D, hydrogen bonds, are much weaker interactions between hydrogen atoms and other electronegative atoms like oxygen or nitrogen.
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