HESI A2
HESI A2 Chemistry
1. How much concentrated HCl should be used to prepare 500 mL of a 0.100 M HCl solution?
- A. 75 mL
- B. 100 mL
- C. 125 mL
- D. 150 mL
Correct answer: B
Rationale: To prepare a 0.100 M HCl solution with a volume of 500 mL, you can use the formula C1V1 = C2V2, where C1 is the concentration of the concentrated HCl solution, V1 is the volume of concentrated HCl solution used, C2 is the desired concentration (0.100 M), and V2 is the final volume (500 mL). Rearranging the formula to solve for V1, you get V1 = (C2V2) / C1. Plugging in the values (0.100 M)(500 mL) / C1 = 100 mL, which means 100 mL of concentrated HCl should be used to prepare 500 mL of a 0.100 M HCl solution. Therefore, the correct answer is 100 mL. Choice A (75 mL), Choice C (125 mL), and Choice D (150 mL) are incorrect as they do not match the calculated volume needed to prepare the desired concentration of HCl solution.
2. What is the correct formula for potassium chloride?
- A. NaCl
- B. KCl
- C. KCl
- D. ClK
Correct answer: B
Rationale: The correct formula for potassium chloride is KCl. In chemical formulas, the symbol for the cation (positive ion) comes first followed by the symbol for the anion (negative ion). Potassium is represented by the symbol K, while chloride is represented by the symbol Cl. Therefore, the formula for potassium chloride is KCl. Choice A (NaCl) is the formula for sodium chloride, not potassium chloride. Choice C is a duplicate of choice B, and choice D (ClK) is an incorrect arrangement of the symbols for potassium and chloride.
3. Which of the following is the weakest intermolecular force?
- A. Dipole interactions
- B. Hydrogen bonding
- C. Van der Waals forces
- D. Dispersion forces
Correct answer: D
Rationale: Dispersion forces, also known as London dispersion forces, are the weakest intermolecular forces. They are temporary attractive forces that occur due to momentary shifts in electron distribution within molecules. While dipole interactions, hydrogen bonding, and Van der Waals forces are stronger intermolecular forces, dispersion forces are the weakest because they arise from short-lived fluctuations in electron density. Dipole interactions involve permanent dipoles in molecules, making them stronger than dispersion forces. Hydrogen bonding is stronger than dipole interactions and involves hydrogen atoms bonded to highly electronegative atoms. Van der Waals forces encompass dipole-dipole interactions and dispersion forces, making them stronger than dispersion forces alone.
4. What effect does increasing the surface area of a reactant have?
- A. Decreases the reaction rate
- B. Has no effect
- C. Increases the reaction rate
- D. Stops the reaction
Correct answer: C
Rationale: Increasing the surface area of a reactant leads to more particles being exposed to the reaction, which in turn increases the reaction rate. This is because a larger surface area provides more sites for collisions between reacting particles, resulting in a higher frequency of successful collisions and thus accelerating the reaction. Choice A, 'Decreases the reaction rate,' is incorrect because increasing surface area actually accelerates the reaction. Choice B, 'Has no effect,' is incorrect as increasing surface area does have a significant effect on the reaction rate. Choice D, 'Stops the reaction,' is incorrect as increasing surface area does not stop the reaction but rather enhances it.
5. Which gas is produced when an acid reacts with a carbonate?
- A. Carbon dioxide
- B. Oxygen
- C. Hydrogen
- D. Nitrogen
Correct answer: A
Rationale: When an acid reacts with a carbonate, the chemical reaction typically yields carbon dioxide gas. Carbon dioxide is formed due to the chemical reaction between the acid and the carbonate, releasing this gas as a product. Therefore, the correct answer is 'Carbon dioxide.' Choices B, C, and D are incorrect as oxygen, hydrogen, and nitrogen are not the gases produced in this specific acid-carbonate reaction.
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