polarity is based on what
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HESI A2

Chemistry HESI A2 Quizlet

1. What determines polarity in a molecule?

Correct answer: C

Rationale: Polarity in a molecule is determined by the difference in electronegativity between the atoms forming the bond. The greater the difference in electronegativity, the more polar the bond and molecule become. This difference leads to an uneven distribution of electron density within the bond, creating partial positive and negative charges on the atoms involved. Choices A, B, and D are incorrect. Bond length and strength do not determine polarity, and molecular weight is not directly related to the polarity of a molecule.

2. The molar mass of glucose is 180 g/mol. If an IV solution contains 5 g of glucose in 100 g of water, what is the molarity of the solution?

Correct answer: C

Rationale: To calculate the molarity of the solution, we first need to determine the moles of solute (glucose) and solvent (water) separately. The molar mass of glucose is 180 g/mol. First, calculate the moles of glucose: 5 g / 180 g/mol = 0.02778 mol of glucose. Next, calculate the moles of water: 100 g / 18 g/mol = 5.56 mol of water. Now, calculate the total moles in the solution: 0.02778 mol glucose + 5.56 mol water = 5.5878 mol. Finally, calculate the molarity: Molarity = moles of solute / liters of solution. Since the total mass of the solution is 100 g + 5 g = 105 g = 0.105 kg, which is equal to 0.105 L, the molarity is 5.5878 mol / 0.105 L = 53.22 M, which rounds to 2.8M. Therefore, the correct answer is 2.8M. Choices A, B, and D are incorrect because they do not reflect the accurate molarity calculation based on the moles of solute and volume of the solution.

3. What is the pH of acids?

Correct answer: B

Rationale: The correct answer is B: < 7. Acids have a pH lower than 7, indicating higher acidity. A pH below 7 signifies an acidic solution, with lower values indicating stronger acids. Choice A (7.5) is incorrect as it is greater than 7, which is alkaline. Choice C (> 7) is incorrect as values greater than 7 represent alkaline/basic solutions. Choice D (7) is incorrect because a pH of 7 is neutral, not acidic.

4. Which of these types of intermolecular force is the strongest?

Correct answer: D

Rationale: Hydrogen bonding is the strongest type of intermolecular force among the options provided. It occurs when a hydrogen atom is covalently bonded to a highly electronegative atom (such as nitrogen, oxygen, or fluorine) and forms a strong electrostatic attraction with an unshared pair of electrons on another electronegative atom. This type of bond is stronger than dipole-dipole interactions, London dispersion forces, and Keesom interactions due to the significant electronegativity difference between the hydrogen and the electronegative atom involved in the bond. The presence of hydrogen bonding contributes to unique properties in substances, such as high boiling and melting points, making it a crucial force in various biological and chemical processes.

5. What type of reaction occurs when an acid and a base react to form water and salt?

Correct answer: A

Rationale: A neutralization reaction is the correct answer. In this type of reaction, an acid and a base combine to form water and salt. The acid donates a proton (H+) to the base, forming water, while the remaining ions combine to form a salt. This reaction results in the neutralization of both the acid and the base, hence the name 'neutralization reaction.' Choice B, decomposition reaction, is incorrect because it refers to a reaction where a compound breaks down into simpler substances. Choice C, combustion reaction, is incorrect as it involves a substance reacting with oxygen to produce heat and light. Choice D, redox reaction, is incorrect because it involves the transfer of electrons between reactants.

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