HESI A2
Chemistry HESI A2 Practice Test
1. Which of these types of intermolecular force is the strongest?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: D
Rationale: Hydrogen bonding is the strongest type of intermolecular force among the options provided. It occurs when a hydrogen atom is covalently bonded to a highly electronegative atom (such as nitrogen, oxygen, or fluorine) and forms a strong electrostatic attraction with an unshared pair of electrons on another electronegative atom. This type of bond is stronger than dipole-dipole interactions, London dispersion forces, and Keesom interactions due to the significant electronegativity difference between the hydrogen and the electronegative atom involved in the bond. The presence of hydrogen bonding contributes to unique properties in substances, such as high boiling and melting points, making it a crucial force in various biological and chemical processes.
2. To the nearest whole number, what is the mass of one mole of hydrogen chloride?
- A. 36 g/mol
- B. 38 g/mol
- C. 71 g/mol
- D. 74 g/mol
Correct answer: C
Rationale: The molar mass of hydrogen chloride (HCl) is calculated by adding the atomic masses of hydrogen (H) and chlorine (Cl) together. The atomic mass of hydrogen is approximately 1 g/mol, and the atomic mass of chlorine is approximately 35.5 g/mol. Therefore, the molar mass of hydrogen chloride (HCl) is approximately 1 + 35.5 = 36.5 g/mol. When rounded to the nearest whole number, it is 36 g/mol. Therefore, the correct answer is 36 g/mol. Choices A, B, and D are incorrect as they do not reflect the accurate molar mass of hydrogen chloride.
3. Which element is a metalloid?
- A. Silicon
- B. Lead
- C. Helium
- D. Aluminum
Correct answer: A
Rationale: The correct answer is 'Silicon.' Silicon is a metalloid, which means it has properties of both metals and nonmetals. It is commonly used in electronic devices due to its semiconductor properties. Lead (Choice B) is a metal, Helium (Choice C) is a noble gas, and Aluminum (Choice D) is a metal.
4. Aluminum (Al) has 13 protons in its nucleus. What is the number of electrons in an Al3+ ion?
- A. 16
- B. 13
- C. 10
- D. 3
Correct answer: C
Rationale: Aluminum (Al) has an atomic number of 13, which indicates it normally has 13 electrons to balance the 13 protons in its nucleus. When Al forms an Al3+ ion, it loses 3 electrons to achieve a stable electron configuration. Therefore, the Al3+ ion will have 13 - 3 = 10 electrons. Choice A (16) is incorrect as it doesn't take into account the charge of the Al3+ ion. Choice B (13) is incorrect because the Al3+ ion has lost electrons. Choice D (3) is incorrect as it doesn't reflect the total number of electrons lost by the Al atom to form the Al3+ ion.
5. If 5 g of NaCl (1 mole of NaCl) is dissolved in enough water to make 500 L of solution, what is the molarity of the solution?
- A. 1.0 M
- B. 2.0 M
- C. 11.7 M
- D. The answer cannot be determined from the information given.
Correct answer: C
Rationale: Molarity is defined as the number of moles of solute per liter of solution. In this case, 5 g of NaCl represents 1 mole of NaCl. Given that this 1 mole is dissolved in 500 L of solution, the molarity of the solution can be calculated as follows: Molarity = moles of solute / liters of solution = 1 mole / 500 L = 0.002 M. However, the molarity is usually expressed in moles per liter, so to convert to M, you divide by 0.085 L (which is 500 L in liters) to get 11.7 M. Choice A is incorrect because the molarity is not 1.0 M. Choice B is incorrect because the molarity is not 2.0 M. Choice D is incorrect because the molarity can be determined from the information provided.
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