HESI A2
Chemistry HESI A2 Practice Test
1. Which of these types of intermolecular force is the strongest?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: D
Rationale: Hydrogen bonding is the strongest type of intermolecular force among the options provided. It occurs when a hydrogen atom is covalently bonded to a highly electronegative atom (such as nitrogen, oxygen, or fluorine) and forms a strong electrostatic attraction with an unshared pair of electrons on another electronegative atom. This type of bond is stronger than dipole-dipole interactions, London dispersion forces, and Keesom interactions due to the significant electronegativity difference between the hydrogen and the electronegative atom involved in the bond. The presence of hydrogen bonding contributes to unique properties in substances, such as high boiling and melting points, making it a crucial force in various biological and chemical processes.
2. Here are the solubilities of four substances at 0°C, in grams of solute per 100 mL of water. If the temperature increases to 20°C, what would you expect to happen to the solubility figures?
- A. Citric acid and potassium phosphate will decrease; nitrogen and oxygen will increase.
- B. Citric acid and potassium phosphate will increase; nitrogen and oxygen will decrease.
- C. All four figures will increase.
- D. All four figures will decrease.
Correct answer: C
Rationale: Solubility generally tends to increase with temperature for most solid solutes in liquid solvents due to higher kinetic energy leading to better solute-solvent interactions. As the temperature increases from 0°C to 20°C, all four solubility figures are expected to increase. Choice A is incorrect because solubility tends to increase with temperature. Choice B is incorrect as well for the same reason. Choice D is incorrect because the solubility of solid solutes typically increases with temperature.
3. What number represents the number of protons an element has?
- A. Atomic mass
- B. Mass number
- C. Atomic number
- D. Neutron number
Correct answer: C
Rationale: The correct answer is C, atomic number. The atomic number corresponds to the number of protons in an element. This number is unique to each element and determines its placement on the periodic table. It is equal to the number of protons found in the nucleus of an atom of that element. Choice A, atomic mass, represents the average mass of an element's isotopes. Choice B, mass number, is the sum of protons and neutrons in an atom. Choice D, neutron number, specifically refers to the count of neutrons in an atom and not protons.
4. Which one is not a hydrocarbon?
- A. Methane (CH4)
- B. Pyridine (C5H5N)
- C. Ethane (C2H6)
- D. Propane (C3H8)
Correct answer: B
Rationale: The correct answer is B, Pyridine (C5H5N). Pyridine is not a hydrocarbon because it contains nitrogen (N) in its molecular structure, in addition to carbon (C) and hydrogen (H) atoms. Hydrocarbons consist solely of carbon and hydrogen atoms. Methane (CH4), ethane (C2H6), and propane (C3H8) are all examples of hydrocarbons as they only contain carbon and hydrogen atoms, making them organic compounds known for their combustion properties.
5. What is stoichiometry?
- A. The study of energy changes in chemical reactions
- B. The study of the mass relationships in chemical reactions
- C. The study of atomic structure
- D. The study of molecular geometry
Correct answer: B
Rationale: Stoichiometry is the branch of chemistry that deals with the quantitative relationships between reactants and products in chemical reactions. It focuses on the calculation of the amounts of substances consumed and produced in a reaction based on the balanced chemical equation. Choice A is incorrect because the study of energy changes in chemical reactions falls under thermodynamics. Choice C is incorrect as atomic structure is related to the arrangement of atoms within molecules. Choice D is incorrect as molecular geometry deals with the spatial arrangement of atoms within molecules.
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