HESI A2
Chemistry HESI A2 Practice Test
1. Which of these types of intermolecular force is the strongest?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: D
Rationale: Hydrogen bonding is the strongest type of intermolecular force among the options provided. It occurs when a hydrogen atom is covalently bonded to a highly electronegative atom (such as nitrogen, oxygen, or fluorine) and forms a strong electrostatic attraction with an unshared pair of electrons on another electronegative atom. This type of bond is stronger than dipole-dipole interactions, London dispersion forces, and Keesom interactions due to the significant electronegativity difference between the hydrogen and the electronegative atom involved in the bond. The presence of hydrogen bonding contributes to unique properties in substances, such as high boiling and melting points, making it a crucial force in various biological and chemical processes.
2. What are the columns of the periodic table called?
- A. Periods
- B. Families
- C. Groups
- D. Rows
Correct answer: C
Rationale: In the periodic table, columns are referred to as groups, not periods, families, or rows. These groups share similar chemical properties due to the arrangement of elements within each group, which is based on the number of valence electrons. The vertical columns help classify elements with similar characteristics. Periods refer to the rows of the periodic table, while families or groups are the vertical columns.
3. What is a benefit of water's ability to make hydrogen bonds?
- A. Lack of cohesiveness
- B. Low surface tension
- C. Use as a nonpolar solvent
- D. High specific heat
Correct answer: D
Rationale: The correct answer is D, high specific heat. Water's ability to form hydrogen bonds results in a high specific heat capacity, allowing it to absorb and release a large amount of heat energy with minimal temperature change. This property is essential for moderating temperature changes in organisms and maintaining stable environmental conditions for life processes. Choices A, lack of cohesiveness, and C, use as a nonpolar solvent, are incorrect. Water actually has high cohesiveness due to its ability to form hydrogen bonds, and it is a polar solvent, not nonpolar. Choice B, low surface tension, is also incorrect as water's hydrogen bonding contributes to its relatively high surface tension.
4. How are elements arranged in the periodic table?
- A. By their atomic mass
- B. By their chemical properties
- C. By their physical state
- D. By their charge
Correct answer: B
Rationale: Elements are arranged in the periodic table based on their chemical properties, making choice B the correct answer. The periodic table is organized so that elements with similar chemical properties are grouped together in columns, known as groups or families. This arrangement allows for the identification of trends in the behavior of elements and predicting their properties based on their position in the table. Choices A, C, and D are incorrect because the periodic table primarily focuses on the chemical properties of elements, not solely on atomic mass, physical state, or charge.
5. If fifty-six kilograms of a radioactive substance has a half-life of 12 days, how many days will it take the substance to decay naturally to only 7 kilograms?
- A. 8
- B. 12
- C. 36
- D. 48
Correct answer: C
Rationale: To decay from 56 kg to 7 kg, the substance needs to go through 3 half-lives (56 kg ÷ 2 ÷ 2 ÷ 2 = 7 kg). Since each half-life is 12 days, the total time required is 12 days per half-life x 3 half-lives = 36 days. Choice A is incorrect because it does not consider the concept of half-lives. Choice B is incorrect because it represents the duration of a single half-life, not the total time required for the decay. Choice D is incorrect as it does not account for the multiple half-lives needed for the substance to decay from 56 kg to 7 kg.
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