HESI A2
Chemistry HESI A2 Practice Test
1. Which of these types of intermolecular force is the strongest?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: D
Rationale: Hydrogen bonding is the strongest type of intermolecular force among the options provided. It occurs when a hydrogen atom is covalently bonded to a highly electronegative atom (such as nitrogen, oxygen, or fluorine) and forms a strong electrostatic attraction with an unshared pair of electrons on another electronegative atom. This type of bond is stronger than dipole-dipole interactions, London dispersion forces, and Keesom interactions due to the significant electronegativity difference between the hydrogen and the electronegative atom involved in the bond. The presence of hydrogen bonding contributes to unique properties in substances, such as high boiling and melting points, making it a crucial force in various biological and chemical processes.
2. What are positively charged ions called?
- A. Neutrons
- B. Protons
- C. Cations
- D. Electrons
Correct answer: C
Rationale: Positively charged ions are called cations. When an atom loses electrons, it becomes positively charged and is referred to as a cation. Neutrons are neutral particles found in the nucleus of an atom, not charged. Protons are positively charged particles in the nucleus. Electrons are negatively charged particles orbiting the nucleus, not positively charged ions.
3. What does the term amphoteric mean?
- A. A substance that only acts as a base
- B. A substance that can act as both a base and an acid
- C. A substance that only acts as an acid
- D. A substance that acts as neither a base nor an acid
Correct answer: B
Rationale: The term 'amphoteric' refers to substances that have the ability to act as both acids and bases depending on the surrounding conditions. This dual nature allows amphoteric substances to donate or accept protons, making them versatile in various chemical reactions. Choice A is incorrect because amphoteric substances can also act as acids. Choice C is incorrect as amphoteric substances can also act as bases. Choice D is incorrect as amphoteric substances can act as either a base or an acid.
4. Which of the following is the weakest intermolecular force?
- A. Dipole interactions
- B. Hydrogen bonding
- C. Van der Waals forces
- D. Dispersion forces
Correct answer: D
Rationale: Dispersion forces, also known as London dispersion forces, are the weakest intermolecular forces. They are temporary attractive forces that occur due to momentary shifts in electron distribution within molecules. While dipole interactions, hydrogen bonding, and Van der Waals forces are stronger intermolecular forces, dispersion forces are the weakest because they arise from short-lived fluctuations in electron density. Dipole interactions involve permanent dipoles in molecules, making them stronger than dispersion forces. Hydrogen bonding is stronger than dipole interactions and involves hydrogen atoms bonded to highly electronegative atoms. Van der Waals forces encompass dipole-dipole interactions and dispersion forces, making them stronger than dispersion forces alone.
5. What charge do Group IIA elements typically have?
- A. 1
- B. +2
- C. -3
- D. 0
Correct answer: B
Rationale: Group IIA elements belong to the alkaline earth metals group in the periodic table. These elements typically have a charge of +2 because they readily lose two electrons to achieve a stable electron configuration. Therefore, the correct answer is B - +2. Choice A (1) is incorrect because Group IIA elements lose two electrons, not one. Choice C (-3) is incorrect because Group IIA elements do not gain electrons to have a negative charge. Choice D (0) is incorrect because Group IIA elements do lose electrons and have a positive charge, not a neutral charge.
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