which of these types of intermolecular force is strongest
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HESI A2

Chemistry HESI A2 Practice Test

1. Which of these types of intermolecular force is the strongest?

Correct answer: D

Rationale: Hydrogen bonding is the strongest type of intermolecular force among the options provided. It occurs when a hydrogen atom is covalently bonded to a highly electronegative atom (such as nitrogen, oxygen, or fluorine) and forms a strong electrostatic attraction with an unshared pair of electrons on another electronegative atom. This type of bond is stronger than dipole-dipole interactions, London dispersion forces, and Keesom interactions due to the significant electronegativity difference between the hydrogen and the electronegative atom involved in the bond. The presence of hydrogen bonding contributes to unique properties in substances, such as high boiling and melting points, making it a crucial force in various biological and chemical processes.

2. Which two functional groups would you expect an amino acid to contain?

Correct answer: A

Rationale: Amino acids are organic compounds that are characterized by the presence of an amino group (NH2) and a carboxylic acid group (COOH) in their chemical structure. These two functional groups, found in option A, are fundamental components of amino acids and play crucial roles in their classification and biological functions. Option B contains an aldehyde group (CHO) and an amide group (CO-NH), which are not characteristic functional groups of amino acids. Option C includes a hydroxyl group (OH) and an ester group (COOR), which are not typically present in amino acids. Option D presents ether (R-O-R) and carboxylic acid (COOH) functional groups, which do not represent the functional groups commonly found in amino acids.

3. What is the oxidation state of the sulfur atom in sulfuric acid H2SO4?

Correct answer: B

Rationale: In sulfuric acid (H2SO4), sulfur has an oxidation state of +6. The oxidation state is determined by considering the overall charge of the compound and the known oxidation states of other elements. In this case, hydrogen is typically +1, and oxygen is -2. To balance the charges and match the compound's overall charge of 0, sulfur must have an oxidation state of +6. Choice A (4) is incorrect because it doesn't balance the charges in the compound. Choices C (8) and D (10) are also incorrect as they are not valid oxidation states for sulfur in this compound.

4. How many neutrons does carbon-14 have?

Correct answer: B

Rationale: The correct answer is B: 8. Carbon-14 is an isotope of carbon with 6 protons and 8 neutrons. To determine the number of neutrons in an atom, subtract the atomic number (number of protons) from the mass number. In this case, the mass number of carbon-14 is 14, and the atomic number of carbon is 6. Therefore, 14 (mass number) - 6 (atomic number) = 8 neutrons. Choices A, C, and D are incorrect because they do not reflect the correct number of neutrons in a carbon-14 atom.

5. How many pairs of electrons are shared between two atoms in a single bond?

Correct answer: A

Rationale: In a single bond, two atoms share one pair of electrons. This shared pair of electrons is what holds the atoms together in the bond. Therefore, the correct answer is A: 1. Choices B, C, and D are incorrect because they do not represent the number of electron pairs shared in a single bond.

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