HESI A2
Chemistry HESI A2 Practice Test
1. Which of these types of intermolecular force is the strongest?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: D
Rationale: Hydrogen bonding is the strongest type of intermolecular force among the options provided. It occurs when a hydrogen atom is covalently bonded to a highly electronegative atom (such as nitrogen, oxygen, or fluorine) and forms a strong electrostatic attraction with an unshared pair of electrons on another electronegative atom. This type of bond is stronger than dipole-dipole interactions, London dispersion forces, and Keesom interactions due to the significant electronegativity difference between the hydrogen and the electronegative atom involved in the bond. The presence of hydrogen bonding contributes to unique properties in substances, such as high boiling and melting points, making it a crucial force in various biological and chemical processes.
2. Which element would you expect to be least reactive?
- A. Li
- B. Cr
- C. Nd
- D. Xe
Correct answer: D
Rationale: Xenon (Xe) is a noble gas located in Group 18 of the periodic table. Noble gases are known for their stable and unreactive nature due to having a full outer shell of electrons. Therefore, xenon would be expected to be the least reactive among the given elements. Choice A (Li) is a metal in Group 1 of the periodic table, which tends to be reactive, especially with water. Choice B (Cr) is a transition metal known for its reactivity in some forms. Choice C (Nd) is a rare earth element, which can exhibit varying reactivity depending on the compound or environment.
3. Which classification best describes B, Si, As, Te, At, Ge, and Sb that form a staircase pattern on the right side of the periodic table?
- A. Metals
- B. Semimetals
- C. Nonmetals
- D. Ultrametals
Correct answer: B
Rationale: B, Si, As, Te, At, Ge, and Sb are located in a staircase pattern on the periodic table's right side. Elements in this region are known as metalloids or semimetals because they exhibit properties of both metals and nonmetals. They possess characteristics of both metallic and non-metallic elements, making them valuable semiconductors with diverse applications in electronics. Choice A is incorrect because these elements are not considered true metals. Choice C is incorrect as these elements do not display typical nonmetal properties exclusively. Choice D, 'Ultrametals,' is not a recognized classification in chemistry and is therefore incorrect.
4. When balanced, the reaction Fe + O₂ → FeO will be?
- A. 2Fe + 2O₂ → 3FeO
- B. 4Fe + 6O₂ → 6FeO
- C. 2Fe + 3O₂ → 2FeO
- D. 4Fe + 3O₂ → 2FeO
Correct answer: C
Rationale: To balance the chemical equation Fe + O₂ → FeO, the coefficients needed are 2 for Fe and 1 for O. Therefore, the balanced equation becomes 2Fe + O₂ → 2FeO, which translates into 2Fe + 3O₂ → 2FeO. This corresponds to option C. Choice A has the incorrect number of oxygen molecules. Choice B has an incorrect number of Fe atoms on the product side. Choice D also has an incorrect number of Fe atoms on the product side.
5. What is the main component of air?
- A. Oxygen
- B. Nitrogen
- C. Carbon dioxide
- D. Argon
Correct answer: B
Rationale: Nitrogen is the main component of air, constituting approximately 78% of the Earth's atmosphere. Oxygen, carbon dioxide, and argon are also present in smaller amounts, but nitrogen is the most abundant gas in the air. Therefore, the correct answer is B. Choice A, oxygen, is essential for respiration but makes up only about 21% of the atmosphere. Choice C, carbon dioxide, is vital for photosynthesis but exists in trace amounts in the air. Choice D, argon, is a noble gas found in relatively small quantities in the atmosphere.
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