HESI A2
Chemistry HESI A2 Practice Test
1. Which of these types of intermolecular force is the strongest?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: D
Rationale: Hydrogen bonding is the strongest type of intermolecular force among the options provided. It occurs when a hydrogen atom is covalently bonded to a highly electronegative atom (such as nitrogen, oxygen, or fluorine) and forms a strong electrostatic attraction with an unshared pair of electrons on another electronegative atom. This type of bond is stronger than dipole-dipole interactions, London dispersion forces, and Keesom interactions due to the significant electronegativity difference between the hydrogen and the electronegative atom involved in the bond. The presence of hydrogen bonding contributes to unique properties in substances, such as high boiling and melting points, making it a crucial force in various biological and chemical processes.
2. Which is a property of an ionic compound?
- A. Low melting point
- B. Poor conductivity
- C. Shared electrons
- D. Crystalline shape
Correct answer: D
Rationale: Ionic compounds are composed of positively and negatively charged ions that are held together by strong electrostatic forces. These ions arrange themselves in a repeating pattern to form a stable and orderly structure known as a crystalline shape. This is a characteristic property of ionic compounds, making choice D the correct answer. Choices A, B, and C are incorrect because ionic compounds typically have high melting points, good conductivity in the molten or dissolved state, and do not involve shared electrons but rather the transfer of electrons between atoms.
3. To the nearest whole number, what is the mass of one mole of water?
- A. 16 g/mol
- B. 18 g/mol
- C. 20 g/mol
- D. 22 g/mol
Correct answer: B
Rationale: The molar mass of water (H₂O) is calculated by adding the atomic masses of two hydrogen atoms (each with a molar mass of approximately 1 g/mol) and one oxygen atom (with a molar mass of approximately 16 g/mol). Therefore, the molar mass of water is approximately 18 g/mol, making choice B the correct answer. Choice A (16 g/mol) is incorrect because it represents the molar mass of oxygen, not water. Choices C (20 g/mol) and D (22 g/mol) are incorrect as they do not correspond to the molar mass of water.
4. Cobalt-60 has a half-life of 5 years. If you start with 20 g of cobalt-60, how much is left after 10 years?
- A. 15 g
- B. 10 g
- C. 5 g
- D. 2.5 g
Correct answer: C
Rationale: Cobalt-60's half-life of 5 years means that after 5 years, half of the initial amount remains. Therefore, after 10 years, a quarter (half of a half) of the initial amount will remain. Starting with 20 g, after 10 years, 5 g of cobalt-60 will be left. Choice A (15 g) is incorrect because it assumes a linear decrease, not considering the exponential decay characteristic of radioactive substances. Choice B (10 g) is incorrect as it overlooks that after 10 years, more decay has occurred. Choice D (2.5 g) is incorrect as it represents only an eighth of the initial amount after 10 years, not a quarter.
5. Arsenic and silicon are examples of ___________.
- A. metals
- B. nonmetals
- C. metalloids
- D. heavy metals
Correct answer: C
Rationale: Arsenic and silicon are both examples of metalloids. Metalloids have properties that lie between those of metals and nonmetals. They exhibit characteristics of both groups, making them versatile elements with various applications in different industries. Choice A (metals) is incorrect as arsenic and silicon do not exhibit typical metallic properties. Choice B (nonmetals) is incorrect as they do not possess all the properties of nonmetals. Choice D (heavy metals) is incorrect as heavy metals refer to a different group of elements with high atomic weights, and arsenic and silicon are not categorized as heavy metals.
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