which of these types of intermolecular force is strongest

HESI A2

Chemistry HESI A2 Practice Test

1. Which of these types of intermolecular force is the strongest?

A. Dipole-dipole interaction
B. London dispersion force
C. Keesom interaction
D. Hydrogen bonding

Correct answer: D

Rationale: Hydrogen bonding is the strongest type of intermolecular force among the options provided. It occurs when a hydrogen atom is covalently bonded to a highly electronegative atom (such as nitrogen, oxygen, or fluorine) and forms a strong electrostatic attraction with an unshared pair of electrons on another electronegative atom. This type of bond is stronger than dipole-dipole interactions, London dispersion forces, and Keesom interactions due to the significant electronegativity difference between the hydrogen and the electronegative atom involved in the bond. The presence of hydrogen bonding contributes to unique properties in substances, such as high boiling and melting points, making it a crucial force in various biological and chemical processes.

2. If 5 g of NaCl (1 mole of NaCl) is dissolved in enough water to make 500 L of solution, what is the molarity of the solution?

A. 1.0 M
B. 2.0 M
C. 11.7 M
D. The answer cannot be determined from the information given.

Correct answer: C

Rationale: Molarity is defined as the number of moles of solute per liter of solution. In this case, 5 g of NaCl represents 1 mole of NaCl. Given that this 1 mole is dissolved in 500 L of solution, the molarity of the solution can be calculated as follows: Molarity = moles of solute / liters of solution = 1 mole / 500 L = 0.002 M. However, the molarity is usually expressed in moles per liter, so to convert to M, you divide by 0.085 L (which is 500 L in liters) to get 11.7 M. Choice A is incorrect because the molarity is not 1.0 M. Choice B is incorrect because the molarity is not 2.0 M. Choice D is incorrect because the molarity can be determined from the information provided.

3. What is the oxidation state of the nitrogen atom in the compound NH3?

A. -3
B. -1
C. +1
D. +3

Correct answer: B

Rationale: In the compound NH3, nitrogen is bonded to three hydrogen atoms. Hydrogen is always assigned an oxidation state of +1. Since the overall charge of NH3 is zero, the oxidation state of nitrogen must be -1 to balance out the hydrogen's +1 oxidation state. Therefore, the correct oxidation state of the nitrogen atom in NH3 is -1. Choice A (-3) is incorrect because it does not account for the electronegativity of hydrogen. Choice C (+1) and Choice D (+3) are incorrect as the nitrogen atom in NH3 needs to balance the +1 oxidation state of each hydrogen atom, resulting in a total of -3 to maintain the compound's charge neutrality.

4. Why does fluorine have a higher ionization energy than oxygen?

A. Fluorine has a smaller number of neutrons.
B. Fluorine has a larger number of neutrons.
C. Fluorine has a smaller nuclear charge.
D. Fluorine has a larger nuclear charge.

Correct answer: D

Rationale: Fluorine has a higher ionization energy than oxygen because fluorine has a larger nuclear charge. The greater number of protons in the nucleus of fluorine attracts its electrons more strongly, making it harder to remove an electron from a fluorine atom compared to an oxygen atom. Choice A is incorrect as the number of neutrons does not directly affect ionization energy. Choice B is also incorrect for the same reason. Choice C is incorrect because a smaller nuclear charge would result in lower ionization energy, not higher.

5. What does the mass of one mole of a substance represent?

A. Atomic mass
B. Mass number
C. Molecular weight
D. Molar mass

Correct answer: D

Rationale: The mass of one mole of a substance is represented by its molar mass. Molar mass is the mass of one mole of a substance and is expressed in grams per mole. It is calculated by summing the atomic masses of all atoms in a molecule. Therefore, the correct answer is D - 'Molar mass'. Choice A, 'Atomic mass', refers to the average mass of an atom of an element. Choice B, 'Mass number', is the total number of protons and neutrons in an atom's nucleus. Choice C, 'Molecular weight', is the average mass of a molecule relative to 1/12 of the mass of an atom of carbon-12.