HESI A2
Chemistry HESI A2 Practice Test
1. Which of these types of intermolecular force is the strongest?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: D
Rationale: Hydrogen bonding is the strongest type of intermolecular force among the options provided. It occurs when a hydrogen atom is covalently bonded to a highly electronegative atom (such as nitrogen, oxygen, or fluorine) and forms a strong electrostatic attraction with an unshared pair of electrons on another electronegative atom. This type of bond is stronger than dipole-dipole interactions, London dispersion forces, and Keesom interactions due to the significant electronegativity difference between the hydrogen and the electronegative atom involved in the bond. The presence of hydrogen bonding contributes to unique properties in substances, such as high boiling and melting points, making it a crucial force in various biological and chemical processes.
2. Which element would you expect to be least reactive?
- A. Li
- B. Cr
- C. Nd
- D. Xe
Correct answer: D
Rationale: Xenon (Xe) is a noble gas located in Group 18 of the periodic table. Noble gases are known for their stable and unreactive nature due to having a full outer shell of electrons. Therefore, xenon would be expected to be the least reactive among the given elements. Choice A (Li) is a metal in Group 1 of the periodic table, which tends to be reactive, especially with water. Choice B (Cr) is a transition metal known for its reactivity in some forms. Choice C (Nd) is a rare earth element, which can exhibit varying reactivity depending on the compound or environment.
3. What are negatively charged ions called?
- A. Neutrons
- B. Protons
- C. Anions
- D. Cations
Correct answer: C
Rationale: Negatively charged ions are called anions. Anions gain electrons and carry a negative charge, which distinguishes them from cations that are positively charged and neutrons and protons that are subatomic particles found in the nucleus of an atom. Choice A, Neutrons, are neutral subatomic particles found in the nucleus of an atom, not negatively charged ions. Choice B, Protons, are positively charged subatomic particles found in the nucleus of an atom, not negatively charged ions. Choice D, Cations, are positively charged ions that lose electrons, which is opposite to the behavior of negatively charged ions.
4. What type of chemical reaction is represented by AB → A + B?
- A. Synthesis
- B. Decomposition
- C. Single replacement
- D. Double replacement
Correct answer: B
Rationale: The chemical equation AB → A + B represents a decomposition reaction. In a decomposition reaction, a single compound breaks down into two or more simpler substances. In this specific reaction, compound AB is decomposed into its elements, A and B, making it a decomposition reaction. Choice A, Synthesis, involves the combination of two or more substances to form a more complex product, which is not the case here. Choices C and D, Single replacement and Double replacement, involve the exchange of ions between compounds or elements, which is not happening in the given reaction.
5. Which of the following best describes an endothermic reaction?
- A. A reaction that absorbs heat
- B. A reaction that releases heat
- C. A reaction that does not involve heat
- D. A reaction that remains at a constant temperature
Correct answer: A
Rationale: An endothermic reaction is a process that absorbs heat from its surroundings. When a reaction absorbs heat, it leads to a decrease in the temperature of the surroundings, making choice A the correct description. In an endothermic reaction, energy is taken in from the surroundings, resulting in a decrease in temperature around the reaction site. Choice B is incorrect because a reaction that releases heat is known as an exothermic reaction. Choice C is incorrect as all reactions involve heat to some extent. Choice D is incorrect as an endothermic reaction does not remain at a constant temperature but rather absorbs heat, leading to a temperature decrease in the surroundings.
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