HESI A2
Chemistry HESI A2 Practice Test
1. If gas A has four times the molar mass of gas B, you would expect it to diffuse through a plug ___________.
- A. at half the rate of gas B
- B. at twice the rate of gas B
- C. at a quarter the rate of gas B
- D. at four times the rate of gas B
Correct answer: A
Rationale: When comparing the diffusion rates of two gases, according to Graham's law of diffusion, the rate of diffusion is inversely proportional to the square root of the molar mass. If gas A has four times the molar mass of gas B, the square root of the molar masses ratio (4:1) is 2. This means that gas A would diffuse through a plug at half the rate of gas B. Therefore, the correct answer is A, at half the rate of gas B. Choices B, C, and D are incorrect because they do not reflect the correct relationship between the molar masses and the rates of diffusion according to Graham's law.
2. Which best defines the molarity of an aqueous sugar solution?
- A. Grams of sugar per milliliter of solution
- B. Moles of sugar per milliliter of solution
- C. Grams of sugar per liter of solution
- D. Moles of sugar per liter of solution
Correct answer: D
Rationale: The molarity of a solution is defined as the number of moles of solute per liter of solvent. In the case of an aqueous sugar solution, the molarity would be expressed as moles of sugar per liter of solution. This is because molarity is a measurement of the concentration of a solute in a solution based on the number of moles present in a given volume of the solution. Therefore, the correct answer is D. Choices A, B, and C are incorrect because the molarity is specifically defined in terms of moles of solute per liter of solution, not in grams per milliliter or grams per liter. Molarity is a unit of concentration that relates the amount of solute to the volume of the solution, not the mass of the solute.
3. What is the name of the force that holds ionic compounds together?
- A. Covalent bonds
- B. Ionic bonds
- C. Hydrogen bonds
- D. Metallic bonds
Correct answer: B
Rationale: Ionic bonds are the forces that hold ionic compounds together. In ionic compounds, positively and negatively charged ions are held together by electrostatic forces of attraction, forming a stable structure. Covalent bonds involve the sharing of electrons between atoms, not the transfer of electrons like in ionic bonds. Hydrogen bonds are a type of intermolecular force, not the primary force in holding ionic compounds together. Metallic bonds are found in metals and involve a 'sea of electrons' that hold metal atoms together, different from the electrostatic attraction between ions in ionic compounds.
4. Why does fluorine have a higher ionization energy than oxygen?
- A. Fluorine has a smaller number of neutrons.
- B. Fluorine has a larger number of neutrons.
- C. Fluorine has a smaller nuclear charge.
- D. Fluorine has a larger nuclear charge.
Correct answer: D
Rationale: Fluorine has a higher ionization energy than oxygen because fluorine has a larger nuclear charge. The greater number of protons in the nucleus of fluorine attracts its electrons more strongly, making it harder to remove an electron from a fluorine atom compared to an oxygen atom. Choice A is incorrect as the number of neutrons does not directly affect ionization energy. Choice B is also incorrect for the same reason. Choice C is incorrect because a smaller nuclear charge would result in lower ionization energy, not higher.
5. Which of the following represents a hydride ion?
- A. H⁻
- B. H⁺
- C. OH⁻
- D. HCl
Correct answer: A
Rationale: The hydride ion is denoted by H⁻, indicating that it has gained an extra electron to complete its valence shell, resulting in a full octet and a net charge of -1. This ion is commonly found in metal hydrides and plays a significant role in various chemical reactions. Option B, H⁺, represents a proton with a positive charge. Option C, OH⁻, represents the hydroxide ion, consisting of oxygen and hydrogen. Option D, HCl, is a compound composed of hydrogen and chlorine ions, not a hydride ion.
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