HESI A2
Chemistry HESI A2 Practice Test
1. If gas A has four times the molar mass of gas B, you would expect it to diffuse through a plug ___________.
- A. at half the rate of gas B
- B. at twice the rate of gas B
- C. at a quarter the rate of gas B
- D. at four times the rate of gas B
Correct answer: A
Rationale: When comparing the diffusion rates of two gases, according to Graham's law of diffusion, the rate of diffusion is inversely proportional to the square root of the molar mass. If gas A has four times the molar mass of gas B, the square root of the molar masses ratio (4:1) is 2. This means that gas A would diffuse through a plug at half the rate of gas B. Therefore, the correct answer is A, at half the rate of gas B. Choices B, C, and D are incorrect because they do not reflect the correct relationship between the molar masses and the rates of diffusion according to Graham's law.
2. Which of the following types of matter changes in volume with changes in temperature and pressure?
- A. Liquid
- B. Gas
- C. Solid
- D. Plasma
Correct answer: B
Rationale: A gas changes its volume with changes in temperature and pressure due to the particles moving more rapidly at higher temperatures, and pressure affects the space between particles. Liquids have a relatively fixed volume but take the shape of their container. Solids have a definite shape and volume, so they do not change volume with changes in temperature and pressure. Plasma is a state of matter where particles are highly energized and do not have a fixed volume, but it does not exhibit volume changes with temperature and pressure variations.
3. When an acid is added to a base, water and a salt form. What kinds of bonds form in these two compounds?
- A. Liquid and metallic
- B. Polar and nonpolar covalent
- C. Polar covalent and ionic
- D. Ionic only
Correct answer: C
Rationale: In water, the bond formed between the oxygen atom and the hydrogen atoms is a polar covalent bond. The oxygen atom attracts the shared electrons more strongly, creating a partial negative charge on the oxygen and a partial positive charge on the hydrogen atoms. In the salt formed, the bond between the metal cation and the nonmetal anion is predominantly an ionic bond. The metal cation donates electrons to the nonmetal anion, resulting in the formation of oppositely charged ions that are held together by electrostatic attractions. Choices A and B are incorrect because water and salts do not form bonds that are liquid and metallic, or polar and nonpolar covalent. Choice D is incorrect as it oversimplifies the types of bonds present in water and salts, failing to differentiate between the covalent bond in water and the ionic bond in the salt.
4. In which state of matter are particles packed tightly together in a fixed position?
- A. Liquid
- B. Solid
- C. Gas
- D. Plasma
Correct answer: B
Rationale: In a 'solid' state, particles are tightly packed in fixed positions, maintaining a definite shape and volume. This arrangement allows solids to maintain a rigid structure. Liquids have particles that are close together but can move past each other, giving them the ability to flow and take the shape of their container. Gases have particles that are far apart and move freely, leading to their ability to expand to fill any container. Plasma is an ionized gas where particles have high energy levels and are not packed tightly together, making it an uncommon state of matter on Earth.
5. Which of these intermolecular forces might represent attraction between atoms of a noble gas?
- A. Dipole-dipole interaction
- B. London dispersion force
- C. Keesom interaction
- D. Hydrogen bonding
Correct answer: B
Rationale: Noble gases are non-polar molecules without a permanent dipole moment. The only intermolecular force applicable to noble gases is the London dispersion force, also known as Van der Waals forces. This force is a temporary attractive force resulting from the formation of temporary dipoles in non-polar molecules. Dipole-dipole interactions, Keesom interactions, and hydrogen bonding involve significant dipoles or hydrogen atoms bonded to electronegative atoms, which do not apply to noble gases.
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