if gas a has four times the molar mass of gas b you would expect it to diffuse through a plug

HESI A2

Chemistry HESI A2 Practice Test

1. If gas A has four times the molar mass of gas B, you would expect it to diffuse through a plug ___________.

A. at half the rate of gas B
B. at twice the rate of gas B
C. at a quarter the rate of gas B
D. at four times the rate of gas B

Correct answer: A

Rationale: When comparing the diffusion rates of two gases, according to Graham's law of diffusion, the rate of diffusion is inversely proportional to the square root of the molar mass. If gas A has four times the molar mass of gas B, the square root of the molar masses ratio (4:1) is 2. This means that gas A would diffuse through a plug at half the rate of gas B. Therefore, the correct answer is A, at half the rate of gas B. Choices B, C, and D are incorrect because they do not reflect the correct relationship between the molar masses and the rates of diffusion according to Graham's law.

2. Which type of change occurs when no change is made to the chemical composition of a substance?

A. Chemical
B. Physical
C. Nuclear
D. Mechanical

Correct answer: B

Rationale: A physical change refers to alterations in the state of matter without modifying the chemical composition of the substance. Examples of physical changes include changes in state (solid, liquid, gas), shape, size, or phase. In a physical change, the substance may look different or behave differently, but its chemical structure remains the same. On the other hand, chemical changes involve the breaking and forming of chemical bonds, resulting in the creation of entirely new substances with different chemical properties. Nuclear changes involve alterations in the nucleus of an atom, such as radioactive decay. Mechanical changes refer to changes in the position or motion of an object caused by applied forces, like pushing, pulling, or twisting.

3. How many pairs of electrons are shared between two atoms in a single bond?

A. 1
B. 2
C. 3
D. 4

Correct answer: A

Rationale: In a single bond, two atoms share one pair of electrons. This shared pair of electrons is what holds the atoms together in the bond. Therefore, the correct answer is A: 1. Choices B, C, and D are incorrect because they do not represent the number of electron pairs shared in a single bond.

4. Which substance shows a decrease in solubility in water with an increase in temperature?

A. NaCl
B. O
C. KI
D. CaCl

Correct answer: C

Rationale: Potassium iodide (KI) shows a decrease in solubility in water with an increase in temperature. This is due to the dissolution of KI in water being an endothermic process. When the temperature rises, the equilibrium shifts toward the solid state, leading to a decrease in solubility. Therefore, as the temperature increases, KI becomes less soluble in water. Choice A (NaCl) and Choice D (CaCl) do not exhibit a decrease in solubility with an increase in temperature. NaCl and CaCl are generally more soluble in water at higher temperatures. Choice B (Oxygen) is a gas and not typically considered in solubility discussions involving solids or liquids dissolving in water.

5. What is another name for aqueous HI?

A. hydroiodic acid
B. hydrogen monoiodide
C. hydrogen iodide
D. hydriodic acid

Correct answer: D

Rationale: The correct name for aqueous HI is 'hydriodic acid.' When hydrogen iodide (HI) dissolves in water, it forms hydriodic acid. Therefore, 'hydriodic acid' is the appropriate term for aqueous HI. Choice A, 'hydroiodic acid,' is incorrect as it does not reflect the nature of the compound in the aqueous state. Choice B, 'hydrogen monoiodide,' is not a widely recognized term for this compound. Choice C, 'hydrogen iodide,' is the name for HI in the gaseous state, not when it's dissolved in water.