if gas a has four times the molar mass of gas b you would expect it to diffuse through a plug
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HESI A2

Chemistry HESI A2 Practice Test

1. If gas A has four times the molar mass of gas B, you would expect it to diffuse through a plug ___________.

Correct answer: A

Rationale: When comparing the diffusion rates of two gases, according to Graham's law of diffusion, the rate of diffusion is inversely proportional to the square root of the molar mass. If gas A has four times the molar mass of gas B, the square root of the molar masses ratio (4:1) is 2. This means that gas A would diffuse through a plug at half the rate of gas B. Therefore, the correct answer is A, at half the rate of gas B. Choices B, C, and D are incorrect because they do not reflect the correct relationship between the molar masses and the rates of diffusion according to Graham's law.

2. Which compound has a nonpolar bond in which the electrons are shared equally?

Correct answer: D

Rationale: The compound CH₄, methane, has a nonpolar bond where carbon and hydrogen share electrons equally. This occurs because carbon and hydrogen have similar electronegativities, meaning they have equal abilities to attract shared electrons. Consequently, a nonpolar covalent bond is formed due to the balanced sharing of electrons between these atoms. Choices A, B, and C do not have nonpolar bonds with electrons shared equally. In H₂O (water), there are polar covalent bonds due to the difference in electronegativity between hydrogen and oxygen. In NH₃ (ammonia), the nitrogen-hydrogen bonds are polar because of the electronegativity difference. In Cl₂ (chlorine gas), the Cl-Cl bond is nonpolar, but the question specifies a compound, not an element, and chlorine does not share its electrons equally with another element in a compound.

3. Which of the following compounds is ionic?

Correct answer: A

Rationale: The correct answer is NaCl (sodium chloride). Ionic compounds are formed by the transfer of electrons between a metal and a nonmetal. In NaCl, sodium (Na) is a metal, and chlorine (Cl) is a nonmetal. Sodium donates an electron to chlorine, leading to the formation of the ionic bond between them. This results in the formation of an ionic compound, where positively charged sodium ions are attracted to negatively charged chloride ions, creating a crystal lattice structure. Choices B, C, and D are not ionic compounds. H₂O (water) is a covalent compound formed by the sharing of electrons between two nonmetals (oxygen and hydrogen). HCl (hydrogen chloride) and NH₃ (ammonia) are also covalent compounds involving nonmetals sharing electrons, not transferring them.

4. What are the columns of the periodic table called?

Correct answer: C

Rationale: In the periodic table, columns are referred to as groups, not periods, families, or rows. These groups share similar chemical properties due to the arrangement of elements within each group, which is based on the number of valence electrons. The vertical columns help classify elements with similar characteristics. Periods refer to the rows of the periodic table, while families or groups are the vertical columns.

5. Why does the diffusion rate increase as a substance is heated?

Correct answer: A

Rationale: The correct answer is A. When a substance is heated, the kinetic energy of particles increases, causing them to move faster. This increased movement allows the particles to spread out more rapidly, leading to a higher diffusion rate. Choice B is incorrect because heating does not directly affect the space between particles. Choice C is incorrect because heating does not necessarily lead to a decrease in the density of particles. Choice D is incorrect because the size of particles does not necessarily increase when a substance is heated. Therefore, the correct explanation for the increase in diffusion rate is the rise in kinetic energy of particles.

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