if gas a has four times the molar mass of gas b you would expect it to diffuse through a plug

HESI A2

Chemistry HESI A2 Practice Test

1. If gas A has four times the molar mass of gas B, you would expect it to diffuse through a plug ___________.

A. at half the rate of gas B
B. at twice the rate of gas B
C. at a quarter the rate of gas B
D. at four times the rate of gas B

Correct answer: A

Rationale: When comparing the diffusion rates of two gases, according to Graham's law of diffusion, the rate of diffusion is inversely proportional to the square root of the molar mass. If gas A has four times the molar mass of gas B, the square root of the molar masses ratio (4:1) is 2. This means that gas A would diffuse through a plug at half the rate of gas B. Therefore, the correct answer is A, at half the rate of gas B. Choices B, C, and D are incorrect because they do not reflect the correct relationship between the molar masses and the rates of diffusion according to Graham's law.

2. Why does the diffusion rate increase as a substance is heated?

A. The kinetic energy of particles increases.
B. The space between particles increases.
C. The density of particles decreases.
D. The size of particles increases.

Correct answer: A

Rationale: The correct answer is A. When a substance is heated, the kinetic energy of particles increases, causing them to move faster. This increased movement allows the particles to spread out more rapidly, leading to a higher diffusion rate. Choice B is incorrect because heating does not directly affect the space between particles. Choice C is incorrect because heating does not necessarily lead to a decrease in the density of particles. Choice D is incorrect because the size of particles does not necessarily increase when a substance is heated. Therefore, the correct explanation for the increase in diffusion rate is the rise in kinetic energy of particles.

3. Here are the solubilities of four substances at 0°C, in grams of solute per 100 mL of water. If the temperature increases to 20°C, what would you expect to happen to the solubility figures?

A. Citric acid and potassium phosphate will decrease; nitrogen and oxygen will increase.
B. Citric acid and potassium phosphate will increase; nitrogen and oxygen will decrease.
C. All four figures will increase.
D. All four figures will decrease.

Correct answer: C

Rationale: Solubility generally tends to increase with temperature for most solid solutes in liquid solvents due to higher kinetic energy leading to better solute-solvent interactions. As the temperature increases from 0°C to 20°C, all four solubility figures are expected to increase. Choice A is incorrect because solubility tends to increase with temperature. Choice B is incorrect as well for the same reason. Choice D is incorrect because the solubility of solid solutes typically increases with temperature.

4. Which two functional groups would you expect an amino acid to contain?

A. R-NH2 and R-COOH
B. R-CHO and R-CO-NH
C. R-OH and R-COOR
D. R-O-R and R-COOH

Correct answer: A

Rationale: Amino acids are organic compounds that are characterized by the presence of an amino group (NH2) and a carboxylic acid group (COOH) in their chemical structure. These two functional groups, found in option A, are fundamental components of amino acids and play crucial roles in their classification and biological functions. Option B contains an aldehyde group (CHO) and an amide group (CO-NH), which are not characteristic functional groups of amino acids. Option C includes a hydroxyl group (OH) and an ester group (COOR), which are not typically present in amino acids. Option D presents ether (R-O-R) and carboxylic acid (COOH) functional groups, which do not represent the functional groups commonly found in amino acids.

5. What is the net charge of an ionic compound?

A. 0
B. -1
C. +1
D. Variable

Correct answer: A

Rationale: The correct answer is A: 0. Ionic compounds have a net charge of 0 because they are formed by the combination of positively charged ions (cations) and negatively charged ions (anions) in a way that neutralizes their charges. This balanced combination results in an electrically neutral compound. Therefore, the net charge of an ionic compound is typically 0. Choices B, C, and D are incorrect because ionic compounds are designed to have a total neutral charge, with the positive charges balancing out the negative charges.