HESI A2
Chemistry HESI A2 Practice Test
1. If gas A has four times the molar mass of gas B, you would expect it to diffuse through a plug ___________.
- A. at half the rate of gas B
- B. at twice the rate of gas B
- C. at a quarter the rate of gas B
- D. at four times the rate of gas B
Correct answer: A
Rationale: When comparing the diffusion rates of two gases, according to Graham's law of diffusion, the rate of diffusion is inversely proportional to the square root of the molar mass. If gas A has four times the molar mass of gas B, the square root of the molar masses ratio (4:1) is 2. This means that gas A would diffuse through a plug at half the rate of gas B. Therefore, the correct answer is A, at half the rate of gas B. Choices B, C, and D are incorrect because they do not reflect the correct relationship between the molar masses and the rates of diffusion according to Graham's law.
2. Cobalt-60 has a half-life of 5 years. If you start with 20 g of cobalt-60, how much is left after 10 years?
- A. 15 g
- B. 10 g
- C. 5 g
- D. 2.5 g
Correct answer: C
Rationale: Cobalt-60's half-life of 5 years means that after 5 years, half of the initial amount remains. Therefore, after 10 years, a quarter (half of a half) of the initial amount will remain. Starting with 20 g, after 10 years, 5 g of cobalt-60 will be left. Choice A (15 g) is incorrect because it assumes a linear decrease, not considering the exponential decay characteristic of radioactive substances. Choice B (10 g) is incorrect as it overlooks that after 10 years, more decay has occurred. Choice D (2.5 g) is incorrect as it represents only an eighth of the initial amount after 10 years, not a quarter.
3. Which type of chemical bond is the strongest?
- A. Ionic
- B. Hydrogen
- C. Covalent
- D. Metallic
Correct answer: C
Rationale: Covalent bonds, especially those formed between non-metals, are the strongest type of chemical bond. In covalent bonds, atoms share electrons, creating a strong bond that requires a significant amount of energy to break. Choice A, ionic bonds, are strong but generally weaker than covalent bonds as they involve the transfer of electrons rather than sharing. Choice B, hydrogen bonds, are relatively weak intermolecular forces, not true chemical bonds. Choice D, metallic bonds, are strong but typically not as strong as covalent bonds. Metallic bonds involve a 'sea of electrons' shared between metal atoms, providing strength but with less directional bonding compared to covalent bonds.
4. What are the 3 types of radiation in nuclear chemistry?
- A. Alpha, Beta, Delta
- B. Alpha, Beta, Gamma
- C. Gamma, Beta, Delta
- D. Delta, Beta, Gamma
Correct answer: B
Rationale: The correct answer is B: Alpha, Beta, Gamma. In nuclear chemistry, the 3 types of radiation are alpha, beta, and gamma radiation. Alpha radiation consists of helium nuclei, beta radiation involves electrons or positrons, and gamma radiation is electromagnetic radiation of high frequency. Choice A is incorrect because 'Delta' is not a type of radiation in nuclear chemistry. Choice C is incorrect as it does not list alpha radiation. Choice D is incorrect as it lists the types in the wrong order and includes 'Delta' instead of alpha radiation.
5. Why does fluorine have a higher ionization energy than oxygen?
- A. Fluorine has a smaller number of neutrons.
- B. Fluorine has a larger number of neutrons.
- C. Fluorine has a smaller nuclear charge.
- D. Fluorine has a larger nuclear charge.
Correct answer: D
Rationale: Fluorine has a higher ionization energy than oxygen because fluorine has a larger nuclear charge. The greater number of protons in the nucleus of fluorine attracts its electrons more strongly, making it harder to remove an electron from a fluorine atom compared to an oxygen atom. Choice A is incorrect as the number of neutrons does not directly affect ionization energy. Choice B is also incorrect for the same reason. Choice C is incorrect because a smaller nuclear charge would result in lower ionization energy, not higher.
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