HESI A2
Chemistry HESI A2 Practice Test
1. If gas A has four times the molar mass of gas B, you would expect it to diffuse through a plug ___________.
- A. at half the rate of gas B
- B. at twice the rate of gas B
- C. at a quarter the rate of gas B
- D. at four times the rate of gas B
Correct answer: A
Rationale: When comparing the diffusion rates of two gases, according to Graham's law of diffusion, the rate of diffusion is inversely proportional to the square root of the molar mass. If gas A has four times the molar mass of gas B, the square root of the molar masses ratio (4:1) is 2. This means that gas A would diffuse through a plug at half the rate of gas B. Therefore, the correct answer is A, at half the rate of gas B. Choices B, C, and D are incorrect because they do not reflect the correct relationship between the molar masses and the rates of diffusion according to Graham's law.
2. What type of bond is an electrostatic attraction between two oppositely charged ions?
- A. Covalent
- B. Metallic
- C. Ionic
- D. Hydrogen
Correct answer: C
Rationale: An ionic bond forms when one atom transfers electrons to another, resulting in the formation of positively and negatively charged ions. The attraction between these oppositely charged ions creates an electrostatic bond, known as an ionic bond. Choice A, covalent bonds, involve the sharing of electrons, not the transfer. Choice B, metallic bonds, occur between metal atoms and involve a 'sea of electrons' that are delocalized. Choice D, hydrogen bonds, are much weaker interactions between hydrogen atoms and other electronegative atoms like oxygen or nitrogen.
3. On the periodic table, where are atoms with the largest atomic radius located?
- A. At the top of their group
- B. In the middle of their group
- C. At the bottom of their group
- D. Along the right-hand side
Correct answer: C
Rationale: Atoms with the largest atomic radius are located at the bottom of their group on the periodic table. This is because atomic radius increases down a group due to the addition of more energy levels or shells of electrons. As you move down a group, the outermost electrons are further away from the nucleus, leading to an increase in atomic radius. Choice A 'At the top of their group' is incorrect because atomic radius decreases going up within a group. Choice B 'In the middle of their group' is incorrect as the atomic radius generally increases as you go down a group, not in the middle. Choice D 'Along the right-hand side' is incorrect because atomic radius tends to decrease from left to right across a period on the periodic table due to increased nuclear charge and effective nuclear charge.
4. What is the correct formula for silver hydroxide?
- A. AgO
- B. AgOH
- C. AgH
- D. AgH₂O
Correct answer: B
Rationale: The correct formula for silver hydroxide is AgOH. Silver hydroxide is formed by the combination of the silver ion (Ag⁺) with the hydroxide ion (OH⁻) to create AgOH. It is essential to note that the hydroxide ion consists of one oxygen and one hydrogen atom, thus the formula AgOH. Choices A, C, and D are incorrect as they do not accurately represent the composition of silver hydroxide.
5. How many times more acidic is a substance with a pH of 3 compared to a substance with a pH of 5?
- A. 8
- B. 2
- C. 100
- D. 1,000
Correct answer: D
Rationale: The pH scale is logarithmic, indicating that each pH unit change reflects a 10-fold difference in acidity level. Going from pH 5 to pH 3 involves a difference of 2 units, which translates to a 100-fold increase in acidity level (10^2 = 100 for each unit). Therefore, a substance with a pH of 3 is 1,000 times more acidic than a substance with a pH of 5 (100 * 10 = 1,000). Choice A (8) is incorrect as it does not consider the logarithmic nature of the pH scale. Choice B (2) is incorrect because it represents the difference in pH units, not the increase in acidity level. Choice C (100) is incorrect as it miscalculates the increase in acidity level, which is 1,000 times and not 100 times.
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